Materials Data on H6Pt(NO)4 by Materials Project

doi:10.17188/1680796

Title: Materials Data on H6Pt(NO)4 by Materials Project

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Abstract

PtH6(NO)4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PtH6(NO)4 clusters. Pt6+ is bonded in a rectangular see-saw-like geometry to four N1- atoms. There are two shorter (2.01 Å) and two longer (2.09 Å) Pt–N bond lengths. There are four inequivalent N1- sites. In the first N1- site, N1- is bonded in a trigonal planar geometry to one Pt6+ and two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. In the second N1- site, N1- is bonded in a distorted trigonal non-coplanar geometry to one Pt6+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the third N1- site, N1- is bonded in a distorted trigonal non-coplanar geometry to one Pt6+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the fourth N1- site, N1- is bonded in a trigonal planar geometry to one Pt6+ and two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. There are six inequivalent H1+ sites. In the first H1+ site, H1+more »« less

Publication Date:: 2020-04-30

Other Number(s):: mp-1195303

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; H-N-O-Pt; H6Pt(NO)4; crystal structure

OSTI Identifier:: 1680796

DOI:: https://doi.org/10.17188/1680796

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                    Materials Data on H6Pt(NO)4 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1680796.

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                    Materials Data on H6Pt(NO)4 by Materials Project.  United States.  doi:https://doi.org/10.17188/1680796

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                    2020.  
"Materials Data on H6Pt(NO)4 by Materials Project".  United States.  doi:https://doi.org/10.17188/1680796.  https://www.osti.gov/servlets/purl/1680796. Pub date:Thu Apr 30 00:00:00 EDT 2020

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@article{osti_1680796,

  title        = {Materials Data on H6Pt(NO)4 by Materials Project},

  
  abstractNote = {PtH6(NO)4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PtH6(NO)4 clusters. Pt6+ is bonded in a rectangular see-saw-like geometry to four N1- atoms. There are two shorter (2.01 Å) and two longer (2.09 Å) Pt–N bond lengths. There are four inequivalent N1- sites. In the first N1- site, N1- is bonded in a trigonal planar geometry to one Pt6+ and two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. In the second N1- site, N1- is bonded in a distorted trigonal non-coplanar geometry to one Pt6+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the third N1- site, N1- is bonded in a distorted trigonal non-coplanar geometry to one Pt6+ and three H1+ atoms. There is one shorter (1.02 Å) and two longer (1.03 Å) N–H bond length. In the fourth N1- site, N1- is bonded in a trigonal planar geometry to one Pt6+ and two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one N1- atom. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one N1- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N1- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one N1- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one N1- atom.},

  doi          = {10.17188/1680796},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {4}

}

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DOI: https://doi.org/10.17188/1680796

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