Materials Data on PtS2(NO2)4 by Materials Project

doi:10.17188/1680557

Title: Materials Data on PtS2(NO2)4 by Materials Project

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Abstract

Pt(SO4)2(N2)2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight ammonia molecules and two Pt(SO4)2 clusters. In each Pt(SO4)2 cluster, Pt2+ is bonded in a linear geometry to two equivalent O2- atoms. Both Pt–O bond lengths are 2.02 Å. S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.46–1.59 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Pt2+ and one S2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one S2- atom.

Authors:: The Materials Project

Publication Date:: 2020-05-04

Other Number(s):: mp-1104583

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; PtS2(NO2)4; N-O-Pt-S

OSTI Identifier:: 1680557

DOI:: https://doi.org/10.17188/1680557

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                    The Materials Project. Materials Data on PtS2(NO2)4 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1680557.

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                    The Materials Project. Materials Data on PtS2(NO2)4 by Materials Project.  United States.  doi:https://doi.org/10.17188/1680557

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                    The Materials Project. 2020.  
"Materials Data on PtS2(NO2)4 by Materials Project".  United States.  doi:https://doi.org/10.17188/1680557.  https://www.osti.gov/servlets/purl/1680557. Pub date:Mon May 04 00:00:00 EDT 2020

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@article{osti_1680557,

  title        = {Materials Data on PtS2(NO2)4 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Pt(SO4)2(N2)2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight ammonia molecules and two Pt(SO4)2 clusters. In each Pt(SO4)2 cluster, Pt2+ is bonded in a linear geometry to two equivalent O2- atoms. Both Pt–O bond lengths are 2.02 Å. S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.46–1.59 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Pt2+ and one S2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one S2- atom.},

  doi          = {10.17188/1680557},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1680557

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