U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on La3SiCl3 by Materials Project
Abstract
La3SiCl3 crystallizes in the cubic I4_132 space group. The structure is three-dimensional. La+2.33+ is bonded to two equivalent Si4- and four equivalent Cl1- atoms to form a mixture of edge and corner-sharing LaSi2Cl4 octahedra. The corner-sharing octahedra tilt angles range from 2–3°. Both La–Si bond lengths are 2.93 Å. There are two shorter (3.02 Å) and two longer (3.06 Å) La–Cl bond lengths. Si4- is bonded to six equivalent La+2.33+ atoms to form edge-sharing SiLa6 octahedra. Cl1- is bonded in a rectangular see-saw-like geometry to four equivalent La+2.33+ atoms.
- Publication Date:
- Other Number(s):
- mp-1211457
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cl-La-Si; La3SiCl3; crystal structure
- OSTI Identifier:
- 1680352
- DOI:
- https://doi.org/10.17188/1680352
Citation Formats
Materials Data on La3SiCl3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1680352.
Materials Data on La3SiCl3 by Materials Project. United States. doi:https://doi.org/10.17188/1680352
2020.
"Materials Data on La3SiCl3 by Materials Project". United States. doi:https://doi.org/10.17188/1680352. https://www.osti.gov/servlets/purl/1680352. Pub date:Thu Apr 30 04:00:00 UTC 2020
@article{osti_1680352,
title = {Materials Data on La3SiCl3 by Materials Project},
abstractNote = {La3SiCl3 crystallizes in the cubic I4_132 space group. The structure is three-dimensional. La+2.33+ is bonded to two equivalent Si4- and four equivalent Cl1- atoms to form a mixture of edge and corner-sharing LaSi2Cl4 octahedra. The corner-sharing octahedra tilt angles range from 2–3°. Both La–Si bond lengths are 2.93 Å. There are two shorter (3.02 Å) and two longer (3.06 Å) La–Cl bond lengths. Si4- is bonded to six equivalent La+2.33+ atoms to form edge-sharing SiLa6 octahedra. Cl1- is bonded in a rectangular see-saw-like geometry to four equivalent La+2.33+ atoms.},
doi = {10.17188/1680352},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}
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