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Title: Materials Data on Rb2Pt(CN)4 by Materials Project

Abstract

Rb2Pt(CN)4 crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a body-centered cubic geometry to eight N3- atoms. There are four shorter (3.36 Å) and four longer (3.49 Å) Rb–N bond lengths. In the second Rb1+ site, Rb1+ is bonded in a distorted body-centered cubic geometry to eight N3- atoms. There are a spread of Rb–N bond distances ranging from 3.13–3.38 Å. Pt2+ is bonded in a square co-planar geometry to four C2+ atoms. All Pt–C bond lengths are 1.99 Å. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.18 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted single-bond geometry to four Rb1+ and one C2+ atom. In the second N3- site, N3- is bonded in a distorted single-bond geometry to four Rb1+ and onemore » C2+ atom.« less

Publication Date:
Other Number(s):
mp-1192027
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rb2Pt(CN)4; C-N-Pt-Rb
OSTI Identifier:
1680305
DOI:
https://doi.org/10.17188/1680305

Citation Formats

The Materials Project. Materials Data on Rb2Pt(CN)4 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1680305.
The Materials Project. Materials Data on Rb2Pt(CN)4 by Materials Project. United States. doi:https://doi.org/10.17188/1680305
The Materials Project. 2019. "Materials Data on Rb2Pt(CN)4 by Materials Project". United States. doi:https://doi.org/10.17188/1680305. https://www.osti.gov/servlets/purl/1680305. Pub date:Fri Jan 11 00:00:00 EST 2019
@article{osti_1680305,
title = {Materials Data on Rb2Pt(CN)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb2Pt(CN)4 crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a body-centered cubic geometry to eight N3- atoms. There are four shorter (3.36 Å) and four longer (3.49 Å) Rb–N bond lengths. In the second Rb1+ site, Rb1+ is bonded in a distorted body-centered cubic geometry to eight N3- atoms. There are a spread of Rb–N bond distances ranging from 3.13–3.38 Å. Pt2+ is bonded in a square co-planar geometry to four C2+ atoms. All Pt–C bond lengths are 1.99 Å. There are two inequivalent C2+ sites. In the first C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.18 Å. In the second C2+ site, C2+ is bonded in a single-bond geometry to one Pt2+ and one N3- atom. The C–N bond length is 1.18 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted single-bond geometry to four Rb1+ and one C2+ atom. In the second N3- site, N3- is bonded in a distorted single-bond geometry to four Rb1+ and one C2+ atom.},
doi = {10.17188/1680305},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}