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Title: Materials Data on V2F9 by Materials Project

Abstract

V2F9 crystallizes in the trigonal P3c1 space group. The structure is zero-dimensional and consists of two V2F9 clusters. there are two inequivalent V+4.50+ sites. In the first V+4.50+ site, V+4.50+ is bonded in a 6-coordinate geometry to six F1- atoms. There is three shorter (1.76 Å) and three longer (2.11 Å) V–F bond length. In the second V+4.50+ site, V+4.50+ is bonded in an octahedral geometry to six F1- atoms. There is three shorter (1.74 Å) and three longer (1.93 Å) V–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one V+4.50+ atom. In the second F1- site, F1- is bonded in an L-shaped geometry to two V+4.50+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one V+4.50+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1101228
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; V2F9; F-V
OSTI Identifier:
1679813
DOI:
https://doi.org/10.17188/1679813

Citation Formats

The Materials Project. Materials Data on V2F9 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1679813.
The Materials Project. Materials Data on V2F9 by Materials Project. United States. doi:https://doi.org/10.17188/1679813
The Materials Project. 2020. "Materials Data on V2F9 by Materials Project". United States. doi:https://doi.org/10.17188/1679813. https://www.osti.gov/servlets/purl/1679813. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1679813,
title = {Materials Data on V2F9 by Materials Project},
author = {The Materials Project},
abstractNote = {V2F9 crystallizes in the trigonal P3c1 space group. The structure is zero-dimensional and consists of two V2F9 clusters. there are two inequivalent V+4.50+ sites. In the first V+4.50+ site, V+4.50+ is bonded in a 6-coordinate geometry to six F1- atoms. There is three shorter (1.76 Å) and three longer (2.11 Å) V–F bond length. In the second V+4.50+ site, V+4.50+ is bonded in an octahedral geometry to six F1- atoms. There is three shorter (1.74 Å) and three longer (1.93 Å) V–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one V+4.50+ atom. In the second F1- site, F1- is bonded in an L-shaped geometry to two V+4.50+ atoms. In the third F1- site, F1- is bonded in a single-bond geometry to one V+4.50+ atom.},
doi = {10.17188/1679813},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}