U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on LuFe5P3 by Materials Project
Abstract
LuFe5P3 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Lu is bonded in a 6-coordinate geometry to ten Fe and six P atoms. There are a spread of Lu–Fe bond distances ranging from 2.92–3.10 Å. There are a spread of Lu–P bond distances ranging from 2.76–2.84 Å. There are five inequivalent Fe sites. In the first Fe site, Fe is bonded in a 5-coordinate geometry to five P atoms. There are a spread of Fe–P bond distances ranging from 2.25–2.54 Å. In the second Fe site, Fe is bonded to three equivalent Lu and four P atoms to form a mixture of distorted face, edge, and corner-sharing FeLu3P4 tetrahedra. There are a spread of Fe–P bond distances ranging from 2.24–2.28 Å. In the third Fe site, Fe is bonded to three equivalent Lu and four P atoms to form a mixture of distorted face, edge, and corner-sharing FeLu3P4 tetrahedra. There are a spread of Fe–P bond distances ranging from 2.19–2.34 Å. In the fourth Fe site, Fe is bonded to three equivalent Lu and four P atoms to form a mixture of distorted face, edge, and corner-sharing FeLu3P4 tetrahedra. There are two shorter (2.29 Å) and twomore »
- Publication Date:
- Other Number(s):
- mp-1200053
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Fe-Lu-P; LuFe5P3; crystal structure
- OSTI Identifier:
- 1679404
- DOI:
- https://doi.org/10.17188/1679404
Citation Formats
Materials Data on LuFe5P3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1679404.
Materials Data on LuFe5P3 by Materials Project. United States. doi:https://doi.org/10.17188/1679404
2020.
"Materials Data on LuFe5P3 by Materials Project". United States. doi:https://doi.org/10.17188/1679404. https://www.osti.gov/servlets/purl/1679404. Pub date:Fri Jun 05 04:00:00 UTC 2020
@article{osti_1679404,
title = {Materials Data on LuFe5P3 by Materials Project},
abstractNote = {LuFe5P3 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Lu is bonded in a 6-coordinate geometry to ten Fe and six P atoms. There are a spread of Lu–Fe bond distances ranging from 2.92–3.10 Å. There are a spread of Lu–P bond distances ranging from 2.76–2.84 Å. There are five inequivalent Fe sites. In the first Fe site, Fe is bonded in a 5-coordinate geometry to five P atoms. There are a spread of Fe–P bond distances ranging from 2.25–2.54 Å. In the second Fe site, Fe is bonded to three equivalent Lu and four P atoms to form a mixture of distorted face, edge, and corner-sharing FeLu3P4 tetrahedra. There are a spread of Fe–P bond distances ranging from 2.24–2.28 Å. In the third Fe site, Fe is bonded to three equivalent Lu and four P atoms to form a mixture of distorted face, edge, and corner-sharing FeLu3P4 tetrahedra. There are a spread of Fe–P bond distances ranging from 2.19–2.34 Å. In the fourth Fe site, Fe is bonded to three equivalent Lu and four P atoms to form a mixture of distorted face, edge, and corner-sharing FeLu3P4 tetrahedra. There are two shorter (2.29 Å) and two longer (2.30 Å) Fe–P bond lengths. In the fifth Fe site, Fe is bonded to one Lu and four P atoms to form distorted FeLuP4 tetrahedra that share corners with nine FeLu3P4 tetrahedra, edges with five FeLuP4 tetrahedra, and faces with two equivalent FeLu3P4 tetrahedra. There are a spread of Fe–P bond distances ranging from 2.15–2.23 Å. There are three inequivalent P sites. In the first P site, P is bonded in a 9-coordinate geometry to two equivalent Lu and seven Fe atoms. In the second P site, P is bonded in a 9-coordinate geometry to two equivalent Lu and seven Fe atoms. In the third P site, P is bonded in a 9-coordinate geometry to two equivalent Lu and seven Fe atoms.},
doi = {10.17188/1679404},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}