U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on CsV2O5 by Materials Project
Abstract
CsV2O5 crystallizes in the orthorhombic Cmm2 space group. The structure is three-dimensional. Cs1+ is bonded in a 12-coordinate geometry to twelve O2- atoms. There are a spread of Cs–O bond distances ranging from 3.57–3.65 Å. V+4.50+ is bonded to four O2- atoms to form corner-sharing VO4 tetrahedra. There are a spread of V–O bond distances ranging from 1.65–1.83 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Cs1+ and two equivalent V+4.50+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Cs1+ and one V+4.50+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Cs1+ and two equivalent V+4.50+ atoms.
- Publication Date:
- Other Number(s):
- mp-1078919
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cs-O-V; CsV2O5; crystal structure
- OSTI Identifier:
- 1677861
- DOI:
- https://doi.org/10.17188/1677861
Citation Formats
Materials Data on CsV2O5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1677861.
Materials Data on CsV2O5 by Materials Project. United States. doi:https://doi.org/10.17188/1677861
2020.
"Materials Data on CsV2O5 by Materials Project". United States. doi:https://doi.org/10.17188/1677861. https://www.osti.gov/servlets/purl/1677861. Pub date:Mon May 04 04:00:00 UTC 2020
@article{osti_1677861,
title = {Materials Data on CsV2O5 by Materials Project},
abstractNote = {CsV2O5 crystallizes in the orthorhombic Cmm2 space group. The structure is three-dimensional. Cs1+ is bonded in a 12-coordinate geometry to twelve O2- atoms. There are a spread of Cs–O bond distances ranging from 3.57–3.65 Å. V+4.50+ is bonded to four O2- atoms to form corner-sharing VO4 tetrahedra. There are a spread of V–O bond distances ranging from 1.65–1.83 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Cs1+ and two equivalent V+4.50+ atoms. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Cs1+ and one V+4.50+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Cs1+ and two equivalent V+4.50+ atoms.},
doi = {10.17188/1677861},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}