U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on ReTc(PbO3)2 by Materials Project
Abstract
Pb2TcReO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Re7+ is bonded to six equivalent O2- atoms to form ReO6 octahedra that share corners with six equivalent TcO6 octahedra and faces with eight equivalent PbO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Re–O bond lengths are 1.98 Å. Tc1+ is bonded to six equivalent O2- atoms to form TcO6 octahedra that share corners with six equivalent ReO6 octahedra and faces with eight equivalent PbO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Tc–O bond lengths are 2.04 Å. Pb2+ is bonded to twelve equivalent O2- atoms to form PbO12 cuboctahedra that share corners with twelve equivalent PbO12 cuboctahedra, faces with six equivalent PbO12 cuboctahedra, faces with four equivalent ReO6 octahedra, and faces with four equivalent TcO6 octahedra. All Pb–O bond lengths are 2.84 Å. O2- is bonded in a distorted linear geometry to one Re7+, one Tc1+, and four equivalent Pb2+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1079236
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; ReTc(PbO3)2; O-Pb-Re-Tc
- OSTI Identifier:
- 1677834
- DOI:
- https://doi.org/10.17188/1677834
Citation Formats
The Materials Project. Materials Data on ReTc(PbO3)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1677834.
The Materials Project. Materials Data on ReTc(PbO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1677834
The Materials Project. 2020.
"Materials Data on ReTc(PbO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1677834. https://www.osti.gov/servlets/purl/1677834. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1677834,
title = {Materials Data on ReTc(PbO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Pb2TcReO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Re7+ is bonded to six equivalent O2- atoms to form ReO6 octahedra that share corners with six equivalent TcO6 octahedra and faces with eight equivalent PbO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Re–O bond lengths are 1.98 Å. Tc1+ is bonded to six equivalent O2- atoms to form TcO6 octahedra that share corners with six equivalent ReO6 octahedra and faces with eight equivalent PbO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Tc–O bond lengths are 2.04 Å. Pb2+ is bonded to twelve equivalent O2- atoms to form PbO12 cuboctahedra that share corners with twelve equivalent PbO12 cuboctahedra, faces with six equivalent PbO12 cuboctahedra, faces with four equivalent ReO6 octahedra, and faces with four equivalent TcO6 octahedra. All Pb–O bond lengths are 2.84 Å. O2- is bonded in a distorted linear geometry to one Re7+, one Tc1+, and four equivalent Pb2+ atoms.},
doi = {10.17188/1677834},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}