skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on NaAl2H8(ClO2)4 by Materials Project

Abstract

NaH8(Al(O2Cl)2)2 crystallizes in the tetragonal P4/nmm space group. The structure is zero-dimensional and consists of four Al(O2Cl)2 clusters and two NaH8 clusters. In each Al(O2Cl)2 cluster, Al is bonded in an octahedral geometry to four equivalent O and two equivalent Cl atoms. All Al–O bond lengths are 2.08 Å. Both Al–Cl bond lengths are 2.15 Å. O is bonded in a distorted single-bond geometry to one Al atom. Cl is bonded in a single-bond geometry to one Al atom. In each NaH8 cluster, Na is bonded in a 8-coordinate geometry to eight equivalent H atoms. All Na–H bond lengths are 2.19 Å. H is bonded in a distorted L-shaped geometry to one Na and one H atom. The H–H bond length is 0.75 Å.

Publication Date:
Other Number(s):
mp-1211139
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; NaAl2H8(ClO2)4; Al-Cl-H-Na-O
OSTI Identifier:
1677237
DOI:
https://doi.org/10.17188/1677237

Citation Formats

The Materials Project. Materials Data on NaAl2H8(ClO2)4 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1677237.
The Materials Project. Materials Data on NaAl2H8(ClO2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1677237
The Materials Project. 2019. "Materials Data on NaAl2H8(ClO2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1677237. https://www.osti.gov/servlets/purl/1677237. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1677237,
title = {Materials Data on NaAl2H8(ClO2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {NaH8(Al(O2Cl)2)2 crystallizes in the tetragonal P4/nmm space group. The structure is zero-dimensional and consists of four Al(O2Cl)2 clusters and two NaH8 clusters. In each Al(O2Cl)2 cluster, Al is bonded in an octahedral geometry to four equivalent O and two equivalent Cl atoms. All Al–O bond lengths are 2.08 Å. Both Al–Cl bond lengths are 2.15 Å. O is bonded in a distorted single-bond geometry to one Al atom. Cl is bonded in a single-bond geometry to one Al atom. In each NaH8 cluster, Na is bonded in a 8-coordinate geometry to eight equivalent H atoms. All Na–H bond lengths are 2.19 Å. H is bonded in a distorted L-shaped geometry to one Na and one H atom. The H–H bond length is 0.75 Å.},
doi = {10.17188/1677237},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}