U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Co2Ag3SbO6 by Materials Project
Abstract
Ag3Co2SbO6 crystallizes in the monoclinic C2 space group. The structure is three-dimensional. there are four inequivalent Co2+ sites. In the first Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are four shorter (2.12 Å) and two longer (2.13 Å) Co–O bond lengths. In the second Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are a spread of Co–O bond distances ranging from 2.11–2.14 Å. In the third Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are a spread of Co–O bond distances ranging from 2.11–2.14 Å. In the fourth Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are a spread of Co–O bond distances ranging from 2.09–2.15 Å. There are six inequivalent Ag1+ sites. In themore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-1181748
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Co2Ag3SbO6; Ag-Co-O-Sb
- OSTI Identifier:
- 1676583
- DOI:
- https://doi.org/10.17188/1676583
Citation Formats
The Materials Project. Materials Data on Co2Ag3SbO6 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1676583.
The Materials Project. Materials Data on Co2Ag3SbO6 by Materials Project. United States. doi:https://doi.org/10.17188/1676583
The Materials Project. 2020.
"Materials Data on Co2Ag3SbO6 by Materials Project". United States. doi:https://doi.org/10.17188/1676583. https://www.osti.gov/servlets/purl/1676583. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1676583,
title = {Materials Data on Co2Ag3SbO6 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag3Co2SbO6 crystallizes in the monoclinic C2 space group. The structure is three-dimensional. there are four inequivalent Co2+ sites. In the first Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are four shorter (2.12 Å) and two longer (2.13 Å) Co–O bond lengths. In the second Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are a spread of Co–O bond distances ranging from 2.11–2.14 Å. In the third Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are a spread of Co–O bond distances ranging from 2.11–2.14 Å. In the fourth Co2+ site, Co2+ is bonded to six O2- atoms to form CoO6 octahedra that share edges with three equivalent CoO6 octahedra and edges with three equivalent SbO6 octahedra. There are a spread of Co–O bond distances ranging from 2.09–2.15 Å. There are six inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.13 Å. In the second Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.13 Å. In the third Ag1+ site, Ag1+ is bonded in a linear geometry to two O2- atoms. There are one shorter (2.11 Å) and one longer (2.12 Å) Ag–O bond lengths. In the fourth Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.11 Å. In the fifth Ag1+ site, Ag1+ is bonded in a linear geometry to two O2- atoms. Both Ag–O bond lengths are 2.13 Å. In the sixth Ag1+ site, Ag1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Ag–O bond lengths are 2.13 Å. There are two inequivalent Sb5+ sites. In the first Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share edges with six CoO6 octahedra. There are two shorter (2.02 Å) and four longer (2.03 Å) Sb–O bond lengths. In the second Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share edges with six CoO6 octahedra. There are a spread of Sb–O bond distances ranging from 2.02–2.04 Å. There are nine inequivalent O2- sites. In the first O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra. In the second O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra. In the third O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra. In the fourth O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra. In the fifth O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb trigonal pyramids. In the sixth O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb trigonal pyramids. In the seventh O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra. In the eighth O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra. In the ninth O2- site, O2- is bonded to two Co2+, one Ag1+, and one Sb5+ atom to form a mixture of distorted corner and edge-sharing OCo2AgSb tetrahedra.},
doi = {10.17188/1676583},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}
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