U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Rb3SbF12 by Materials Project
Abstract
Rb3SbF12 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent Rb sites. In the first Rb site, Rb is bonded in a cuboctahedral geometry to twelve F atoms. There are a spread of Rb–F bond distances ranging from 2.85–3.11 Å. In the second Rb site, Rb is bonded in a 2-coordinate geometry to eight F atoms. There are a spread of Rb–F bond distances ranging from 2.70–3.25 Å. Sb is bonded in a body-centered cubic geometry to eight F atoms. There are four shorter (1.97 Å) and four longer (2.17 Å) Sb–F bond lengths. There are three inequivalent F sites. In the first F site, F is bonded in a 3-coordinate geometry to two Rb and one Sb atom. In the second F site, F is bonded in a single-bond geometry to one Rb and one Sb atom. In the third F site, F is bonded to four Rb atoms to form a mixture of corner, edge, and face-sharing FRb4 trigonal pyramids.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1209744
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Rb3SbF12; F-Rb-Sb
- OSTI Identifier:
- 1676097
- DOI:
- https://doi.org/10.17188/1676097
Citation Formats
The Materials Project. Materials Data on Rb3SbF12 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1676097.
The Materials Project. Materials Data on Rb3SbF12 by Materials Project. United States. doi:https://doi.org/10.17188/1676097
The Materials Project. 2019.
"Materials Data on Rb3SbF12 by Materials Project". United States. doi:https://doi.org/10.17188/1676097. https://www.osti.gov/servlets/purl/1676097. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1676097,
title = {Materials Data on Rb3SbF12 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb3SbF12 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent Rb sites. In the first Rb site, Rb is bonded in a cuboctahedral geometry to twelve F atoms. There are a spread of Rb–F bond distances ranging from 2.85–3.11 Å. In the second Rb site, Rb is bonded in a 2-coordinate geometry to eight F atoms. There are a spread of Rb–F bond distances ranging from 2.70–3.25 Å. Sb is bonded in a body-centered cubic geometry to eight F atoms. There are four shorter (1.97 Å) and four longer (2.17 Å) Sb–F bond lengths. There are three inequivalent F sites. In the first F site, F is bonded in a 3-coordinate geometry to two Rb and one Sb atom. In the second F site, F is bonded in a single-bond geometry to one Rb and one Sb atom. In the third F site, F is bonded to four Rb atoms to form a mixture of corner, edge, and face-sharing FRb4 trigonal pyramids.},
doi = {10.17188/1676097},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}