U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SmSbS by Materials Project
Abstract
SmSbS is Matlockite structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Sm3+ is bonded in a 5-coordinate geometry to four equivalent Sb1- and five equivalent S2- atoms. There are a spread of Sm–Sb bond distances ranging from 3.36–3.45 Å. There are a spread of Sm–S bond distances ranging from 2.83–2.99 Å. Sb1- is bonded to four equivalent Sm3+ and four equivalent Sb1- atoms to form distorted SbSm4Sb4 hexagonal bipyramids that share corners with four equivalent SbSm4Sb4 hexagonal bipyramids, corners with twelve equivalent SSm5 square pyramids, edges with four equivalent SbSm4Sb4 hexagonal bipyramids, edges with four equivalent SSm5 square pyramids, and faces with four equivalent SbSm4Sb4 hexagonal bipyramids. There are two shorter (2.88 Å) and two longer (2.97 Å) Sb–Sb bond lengths. S2- is bonded to five equivalent Sm3+ atoms to form distorted SSm5 square pyramids that share corners with twelve equivalent SbSm4Sb4 hexagonal bipyramids, corners with four equivalent SSm5 square pyramids, edges with four equivalent SbSm4Sb4 hexagonal bipyramids, and edges with eight equivalent SSm5 square pyramids.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1103612
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; SmSbS; S-Sb-Sm
- OSTI Identifier:
- 1675777
- DOI:
- https://doi.org/10.17188/1675777
Citation Formats
The Materials Project. Materials Data on SmSbS by Materials Project. United States: N. p., 2018.
Web. doi:10.17188/1675777.
The Materials Project. Materials Data on SmSbS by Materials Project. United States. doi:https://doi.org/10.17188/1675777
The Materials Project. 2018.
"Materials Data on SmSbS by Materials Project". United States. doi:https://doi.org/10.17188/1675777. https://www.osti.gov/servlets/purl/1675777. Pub date:Wed Jul 18 00:00:00 EDT 2018
@article{osti_1675777,
title = {Materials Data on SmSbS by Materials Project},
author = {The Materials Project},
abstractNote = {SmSbS is Matlockite structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Sm3+ is bonded in a 5-coordinate geometry to four equivalent Sb1- and five equivalent S2- atoms. There are a spread of Sm–Sb bond distances ranging from 3.36–3.45 Å. There are a spread of Sm–S bond distances ranging from 2.83–2.99 Å. Sb1- is bonded to four equivalent Sm3+ and four equivalent Sb1- atoms to form distorted SbSm4Sb4 hexagonal bipyramids that share corners with four equivalent SbSm4Sb4 hexagonal bipyramids, corners with twelve equivalent SSm5 square pyramids, edges with four equivalent SbSm4Sb4 hexagonal bipyramids, edges with four equivalent SSm5 square pyramids, and faces with four equivalent SbSm4Sb4 hexagonal bipyramids. There are two shorter (2.88 Å) and two longer (2.97 Å) Sb–Sb bond lengths. S2- is bonded to five equivalent Sm3+ atoms to form distorted SSm5 square pyramids that share corners with twelve equivalent SbSm4Sb4 hexagonal bipyramids, corners with four equivalent SSm5 square pyramids, edges with four equivalent SbSm4Sb4 hexagonal bipyramids, and edges with eight equivalent SSm5 square pyramids.},
doi = {10.17188/1675777},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {7}
}