U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Rb2Li3GaO4 by Materials Project
Abstract
Rb2Li3GaO4 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. Rb1+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 3.15–3.21 Å. There are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to four equivalent O2- atoms to form distorted LiO4 tetrahedra that share corners with two equivalent LiO4 tetrahedra, corners with two equivalent GaO4 tetrahedra, an edgeedge with one GaO4 tetrahedra, and edges with three LiO4 tetrahedra. There are two shorter (2.02 Å) and two longer (2.04 Å) Li–O bond lengths. In the second Li1+ site, Li1+ is bonded to four equivalent O2- atoms to form distorted LiO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra, edges with two equivalent LiO4 tetrahedra, and edges with two equivalent GaO4 tetrahedra. All Li–O bond lengths are 2.00 Å. Ga3+ is bonded to four equivalent O2- atoms to form GaO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra and edges with four LiO4 tetrahedra. All Ga–O bond lengths are 1.89 Å. O2- is bonded in a 4-coordinate geometry to four equivalent Rb1+, three Li1+, and one Ga3+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1209478
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Rb2Li3GaO4; Ga-Li-O-Rb
- OSTI Identifier:
- 1674549
- DOI:
- https://doi.org/10.17188/1674549
Citation Formats
The Materials Project. Materials Data on Rb2Li3GaO4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1674549.
The Materials Project. Materials Data on Rb2Li3GaO4 by Materials Project. United States. doi:https://doi.org/10.17188/1674549
The Materials Project. 2020.
"Materials Data on Rb2Li3GaO4 by Materials Project". United States. doi:https://doi.org/10.17188/1674549. https://www.osti.gov/servlets/purl/1674549. Pub date:Sat May 09 00:00:00 EDT 2020
@article{osti_1674549,
title = {Materials Data on Rb2Li3GaO4 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb2Li3GaO4 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. Rb1+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 3.15–3.21 Å. There are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to four equivalent O2- atoms to form distorted LiO4 tetrahedra that share corners with two equivalent LiO4 tetrahedra, corners with two equivalent GaO4 tetrahedra, an edgeedge with one GaO4 tetrahedra, and edges with three LiO4 tetrahedra. There are two shorter (2.02 Å) and two longer (2.04 Å) Li–O bond lengths. In the second Li1+ site, Li1+ is bonded to four equivalent O2- atoms to form distorted LiO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra, edges with two equivalent LiO4 tetrahedra, and edges with two equivalent GaO4 tetrahedra. All Li–O bond lengths are 2.00 Å. Ga3+ is bonded to four equivalent O2- atoms to form GaO4 tetrahedra that share corners with four equivalent LiO4 tetrahedra and edges with four LiO4 tetrahedra. All Ga–O bond lengths are 1.89 Å. O2- is bonded in a 4-coordinate geometry to four equivalent Rb1+, three Li1+, and one Ga3+ atom.},
doi = {10.17188/1674549},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}