Materials Data on AgH10Rh(N3O5)2 by Materials Project

doi:10.17188/1674541

Title: Materials Data on AgH10Rh(N3O5)2 by Materials Project

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Abstract

RhAg(NO2)4(NH3)2(H2O)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, four rhodium molecules, eight water molecules, and four Ag(NO2)4 clusters. In each Ag(NO2)4 cluster, Ag1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Ag–O bond distances ranging from 2.44–2.87 Å. There are four inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.25 Å. In the second N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.25 Å) N–O bond length. In the third N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. In the fourth N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.25 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N1+more »« less

Authors:: The Materials Project

Publication Date:: Sat Jan 12 00:00:00 EST 2019

Other Number(s):: mp-1197263

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; AgH10Rh(N3O5)2; Ag-H-N-O-Rh

OSTI Identifier:: 1674541

DOI:: https://doi.org/10.17188/1674541

Citation Formats


                    The Materials Project. Materials Data on AgH10Rh(N3O5)2 by Materials Project.  United States: N. p., 2019. 
        Web.  doi:10.17188/1674541.

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                    The Materials Project. Materials Data on AgH10Rh(N3O5)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1674541

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                    The Materials Project. 2019.  
"Materials Data on AgH10Rh(N3O5)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1674541.  https://www.osti.gov/servlets/purl/1674541. Pub date:Sat Jan 12 00:00:00 EST 2019

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@article{osti_1674541,

  title        = {Materials Data on AgH10Rh(N3O5)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {RhAg(NO2)4(NH3)2(H2O)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia molecules, four rhodium molecules, eight water molecules, and four Ag(NO2)4 clusters. In each Ag(NO2)4 cluster, Ag1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Ag–O bond distances ranging from 2.44–2.87 Å. There are four inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.25 Å. In the second N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.25 Å) N–O bond length. In the third N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. In the fourth N1+ site, N1+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.25 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N1+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N1+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N1+ atom. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N1+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one Ag1+ and one N1+ atom. In the sixth O2- site, O2- is bonded in a distorted water-like geometry to one Ag1+ and one N1+ atom. In the seventh O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N1+ atom. In the eighth O2- site, O2- is bonded in a single-bond geometry to one Ag1+ and one N1+ atom.},

  doi          = {10.17188/1674541},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Sat Jan 12 00:00:00 EST 2019},

  month        = {Sat Jan 12 00:00:00 EST 2019}

}

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DOI: https://doi.org/10.17188/1674541

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