U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Li2(TmGe)3 by Materials Project
Abstract
Li2(TmGe)3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Li is bonded to four equivalent Tm and four Ge atoms to form a mixture of distorted face, edge, and corner-sharing LiTm4Ge4 tetrahedra. There are a spread of Li–Tm bond distances ranging from 3.12–3.25 Å. There are a spread of Li–Ge bond distances ranging from 2.52–2.67 Å. There are two inequivalent Tm sites. In the first Tm site, Tm is bonded in a 10-coordinate geometry to four equivalent Li and six Ge atoms. There are a spread of Tm–Ge bond distances ranging from 3.00–3.09 Å. In the second Tm site, Tm is bonded in a 5-coordinate geometry to five Ge atoms. There are a spread of Tm–Ge bond distances ranging from 2.91–3.32 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 9-coordinate geometry to three equivalent Li, five Tm, and one Ge atom. The Ge–Ge bond length is 2.57 Å. In the second Ge site, Ge is bonded in a 2-coordinate geometry to two equivalent Li and seven Tm atoms.
- Publication Date:
- Other Number(s):
- mp-1188157
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ge-Li-Tm; Li2(TmGe)3; crystal structure
- OSTI Identifier:
- 1672896
- DOI:
- https://doi.org/10.17188/1672896
Citation Formats
Materials Data on Li2(TmGe)3 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1672896.
Materials Data on Li2(TmGe)3 by Materials Project. United States. doi:https://doi.org/10.17188/1672896
2019.
"Materials Data on Li2(TmGe)3 by Materials Project". United States. doi:https://doi.org/10.17188/1672896. https://www.osti.gov/servlets/purl/1672896. Pub date:Fri Jan 11 04:00:00 UTC 2019
@article{osti_1672896,
title = {Materials Data on Li2(TmGe)3 by Materials Project},
abstractNote = {Li2(TmGe)3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Li is bonded to four equivalent Tm and four Ge atoms to form a mixture of distorted face, edge, and corner-sharing LiTm4Ge4 tetrahedra. There are a spread of Li–Tm bond distances ranging from 3.12–3.25 Å. There are a spread of Li–Ge bond distances ranging from 2.52–2.67 Å. There are two inequivalent Tm sites. In the first Tm site, Tm is bonded in a 10-coordinate geometry to four equivalent Li and six Ge atoms. There are a spread of Tm–Ge bond distances ranging from 3.00–3.09 Å. In the second Tm site, Tm is bonded in a 5-coordinate geometry to five Ge atoms. There are a spread of Tm–Ge bond distances ranging from 2.91–3.32 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 9-coordinate geometry to three equivalent Li, five Tm, and one Ge atom. The Ge–Ge bond length is 2.57 Å. In the second Ge site, Ge is bonded in a 2-coordinate geometry to two equivalent Li and seven Tm atoms.},
doi = {10.17188/1672896},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}