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Title: Materials Data on SbP2AuF12 by Materials Project

Abstract

AuP2F6SbF6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AuP2F6 clusters and two SbF6 clusters. In each AuP2F6 cluster, Au1- is bonded in a linear geometry to two equivalent P5+ atoms. Both Au–P bond lengths are 2.30 Å. P5+ is bonded in a 3-coordinate geometry to one Au1- and three F1- atoms. All P–F bond lengths are 1.55 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In each SbF6 cluster, Sb3+ is bonded in an octahedral geometry to six F1- atoms. There is four shorter (1.92 Å) and two longer (1.93 Å) Sb–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry tomore » one Sb3+ atom.« less

Authors:
Publication Date:
Other Number(s):
mp-1198127
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; SbP2AuF12; Au-F-P-Sb
OSTI Identifier:
1672891
DOI:
https://doi.org/10.17188/1672891

Citation Formats

The Materials Project. Materials Data on SbP2AuF12 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1672891.
The Materials Project. Materials Data on SbP2AuF12 by Materials Project. United States. doi:https://doi.org/10.17188/1672891
The Materials Project. 2019. "Materials Data on SbP2AuF12 by Materials Project". United States. doi:https://doi.org/10.17188/1672891. https://www.osti.gov/servlets/purl/1672891. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1672891,
title = {Materials Data on SbP2AuF12 by Materials Project},
author = {The Materials Project},
abstractNote = {AuP2F6SbF6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AuP2F6 clusters and two SbF6 clusters. In each AuP2F6 cluster, Au1- is bonded in a linear geometry to two equivalent P5+ atoms. Both Au–P bond lengths are 2.30 Å. P5+ is bonded in a 3-coordinate geometry to one Au1- and three F1- atoms. All P–F bond lengths are 1.55 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In each SbF6 cluster, Sb3+ is bonded in an octahedral geometry to six F1- atoms. There is four shorter (1.92 Å) and two longer (1.93 Å) Sb–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1672891},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}