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Title: Materials Data on CoH8S2(NO2)4 by Materials Project

Abstract

Co(SO4)2(NH2)4 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of four ammonia molecules and one Co(SO4)2 ribbon oriented in the (1, 0, 0) direction. In the Co(SO4)2 ribbon, Co2+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Co–O bond distances ranging from 2.03–2.08 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.47–1.53 Å. In the second S2- site, S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.47–1.52 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Co2+ and one S2- atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Co2+ and one S2- atom. In the third O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Co2+ and one S2- atom. In the fourth O2- site, O2- is bonded in a distortedmore » bent 120 degrees geometry to one Co2+ and one S2- atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the eighth O2- site, O2- is bonded in a single-bond geometry to one S2- atom.« less

Publication Date:
Other Number(s):
mp-1226417
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CoH8S2(NO2)4; Co-H-N-O-S
OSTI Identifier:
1672814
DOI:
https://doi.org/10.17188/1672814

Citation Formats

The Materials Project. Materials Data on CoH8S2(NO2)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1672814.
The Materials Project. Materials Data on CoH8S2(NO2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1672814
The Materials Project. 2020. "Materials Data on CoH8S2(NO2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1672814. https://www.osti.gov/servlets/purl/1672814. Pub date:Fri Jun 05 00:00:00 EDT 2020
@article{osti_1672814,
title = {Materials Data on CoH8S2(NO2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Co(SO4)2(NH2)4 crystallizes in the triclinic P1 space group. The structure is one-dimensional and consists of four ammonia molecules and one Co(SO4)2 ribbon oriented in the (1, 0, 0) direction. In the Co(SO4)2 ribbon, Co2+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Co–O bond distances ranging from 2.03–2.08 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.47–1.53 Å. In the second S2- site, S2- is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of S–O bond distances ranging from 1.47–1.52 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Co2+ and one S2- atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Co2+ and one S2- atom. In the third O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Co2+ and one S2- atom. In the fourth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Co2+ and one S2- atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one S2- atom. In the eighth O2- site, O2- is bonded in a single-bond geometry to one S2- atom.},
doi = {10.17188/1672814},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {6}
}