Materials Data on KCo(N3O4)2 by Materials Project

doi:10.17188/1672676

Title: Materials Data on KCo(N3O4)2 by Materials Project

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Abstract

K(NO2)4CoN2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is one-dimensional and consists of four diamino cobalt molecules and two K(NO2)4 ribbons oriented in the (1, 0, 0) direction. In each K(NO2)4 ribbon, K1+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of K–O bond distances ranging from 2.84–3.11 Å. There are four inequivalent N2+ sites. In the first N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.23 Å. In the second N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.25 Å) N–O bond length. In the third N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.22 Å) and one longer (1.23 Å) N–O bond length. In the fourth N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.23 Å) and one longer (1.24 Å) N–O bond length. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in amore »« less

Authors:: The Materials Project

Publication Date:: Thu Apr 30 00:00:00 EDT 2020

Other Number(s):: mp-1201035

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; KCo(N3O4)2; Co-K-N-O

OSTI Identifier:: 1672676

DOI:: https://doi.org/10.17188/1672676

Citation Formats


                    The Materials Project. Materials Data on KCo(N3O4)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1672676.

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                    The Materials Project. Materials Data on KCo(N3O4)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1672676

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                    The Materials Project. 2020.  
"Materials Data on KCo(N3O4)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1672676.  https://www.osti.gov/servlets/purl/1672676. Pub date:Thu Apr 30 00:00:00 EDT 2020

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@article{osti_1672676,

  title        = {Materials Data on KCo(N3O4)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {K(NO2)4CoN2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is one-dimensional and consists of four diamino cobalt molecules and two K(NO2)4 ribbons oriented in the (1, 0, 0) direction. In each K(NO2)4 ribbon, K1+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of K–O bond distances ranging from 2.84–3.11 Å. There are four inequivalent N2+ sites. In the first N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. Both N–O bond lengths are 1.23 Å. In the second N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.24 Å) and one longer (1.25 Å) N–O bond length. In the third N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.22 Å) and one longer (1.23 Å) N–O bond length. In the fourth N2+ site, N2+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.23 Å) and one longer (1.24 Å) N–O bond length. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one N2+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one K1+ and one N2+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to two equivalent K1+ and one N2+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to two equivalent K1+ and one N2+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one N2+ atom. In the sixth O2- site, O2- is bonded in a distorted single-bond geometry to one K1+ and one N2+ atom. In the seventh O2- site, O2- is bonded in a distorted single-bond geometry to one K1+ and one N2+ atom. In the eighth O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent K1+ and one N2+ atom.},

  doi          = {10.17188/1672676},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Apr 30 00:00:00 EDT 2020},

  month        = {Thu Apr 30 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1672676

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