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Title: Materials Data on RbNiC2N2Cl by Materials Project

Abstract

NiRb2NiC4(N2Cl)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional and consists of two nickel molecules and one Rb2NiC4(N2Cl)2 framework. In the Rb2NiC4(N2Cl)2 framework, Rb1+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Rb–Cl bond lengths are 3.56 Å. Ni2+ is bonded in an octahedral geometry to four equivalent N3- and two equivalent Cl1- atoms. All Ni–N bond lengths are 2.00 Å. Both Ni–Cl bond lengths are 2.53 Å. C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a linear geometry to one Ni2+ and one C2+ atom. Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Ni2+ atom.

Publication Date:
Other Number(s):
mp-1104285
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbNiC2N2Cl; C-Cl-N-Ni-Rb
OSTI Identifier:
1665739
DOI:
https://doi.org/10.17188/1665739

Citation Formats

The Materials Project. Materials Data on RbNiC2N2Cl by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1665739.
The Materials Project. Materials Data on RbNiC2N2Cl by Materials Project. United States. doi:https://doi.org/10.17188/1665739
The Materials Project. 2020. "Materials Data on RbNiC2N2Cl by Materials Project". United States. doi:https://doi.org/10.17188/1665739. https://www.osti.gov/servlets/purl/1665739. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1665739,
title = {Materials Data on RbNiC2N2Cl by Materials Project},
author = {The Materials Project},
abstractNote = {NiRb2NiC4(N2Cl)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional and consists of two nickel molecules and one Rb2NiC4(N2Cl)2 framework. In the Rb2NiC4(N2Cl)2 framework, Rb1+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Rb–Cl bond lengths are 3.56 Å. Ni2+ is bonded in an octahedral geometry to four equivalent N3- and two equivalent Cl1- atoms. All Ni–N bond lengths are 2.00 Å. Both Ni–Cl bond lengths are 2.53 Å. C2+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a linear geometry to one Ni2+ and one C2+ atom. Cl1- is bonded in a 5-coordinate geometry to four equivalent Rb1+ and one Ni2+ atom.},
doi = {10.17188/1665739},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}