skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on HW2C9NO10 by Materials Project

Abstract

W2NHO(CO)9 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eighteen formaldehyde molecules and two W2NHO clusters. In each W2NHO cluster, there are two inequivalent W5+ sites. In the first W5+ site, W5+ is bonded in a linear geometry to one N3- and one H1+ atom. The W–N bond length is 1.88 Å. The W–H bond length is 1.94 Å. In the second W5+ site, W5+ is bonded in a single-bond geometry to one H1+ atom. The W–H bond length is 1.93 Å. N3- is bonded in a linear geometry to one W5+ and one O2- atom. The N–O bond length is 1.18 Å. H1+ is bonded in a bent 120 degrees geometry to two W5+ atoms. O2- is bonded in a single-bond geometry to one N3- atom.

Publication Date:
Other Number(s):
mp-1224650
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; HW2C9NO10; C-H-N-O-W
OSTI Identifier:
1665703
DOI:
https://doi.org/10.17188/1665703

Citation Formats

The Materials Project. Materials Data on HW2C9NO10 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1665703.
The Materials Project. Materials Data on HW2C9NO10 by Materials Project. United States. doi:https://doi.org/10.17188/1665703
The Materials Project. 2019. "Materials Data on HW2C9NO10 by Materials Project". United States. doi:https://doi.org/10.17188/1665703. https://www.osti.gov/servlets/purl/1665703. Pub date:Sun Jan 13 00:00:00 EST 2019
@article{osti_1665703,
title = {Materials Data on HW2C9NO10 by Materials Project},
author = {The Materials Project},
abstractNote = {W2NHO(CO)9 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eighteen formaldehyde molecules and two W2NHO clusters. In each W2NHO cluster, there are two inequivalent W5+ sites. In the first W5+ site, W5+ is bonded in a linear geometry to one N3- and one H1+ atom. The W–N bond length is 1.88 Å. The W–H bond length is 1.94 Å. In the second W5+ site, W5+ is bonded in a single-bond geometry to one H1+ atom. The W–H bond length is 1.93 Å. N3- is bonded in a linear geometry to one W5+ and one O2- atom. The N–O bond length is 1.18 Å. H1+ is bonded in a bent 120 degrees geometry to two W5+ atoms. O2- is bonded in a single-bond geometry to one N3- atom.},
doi = {10.17188/1665703},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}