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Title: Materials Data on VCoO3 by Materials Project

Abstract

CoVO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. V4+ is bonded to six equivalent O2- atoms to form VO6 octahedra that share corners with six equivalent VO6 octahedra and faces with eight equivalent CoO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All V–O bond lengths are 1.89 Å. Co2+ is bonded to twelve equivalent O2- atoms to form CoO12 cuboctahedra that share corners with twelve equivalent CoO12 cuboctahedra, faces with six equivalent CoO12 cuboctahedra, and faces with eight equivalent VO6 octahedra. All Co–O bond lengths are 2.67 Å. O2- is bonded in a distorted linear geometry to two equivalent V4+ and four equivalent Co2+ atoms.

Publication Date:
Other Number(s):
mp-1187746
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; VCoO3; Co-O-V
OSTI Identifier:
1665684
DOI:
https://doi.org/10.17188/1665684

Citation Formats

The Materials Project. Materials Data on VCoO3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1665684.
The Materials Project. Materials Data on VCoO3 by Materials Project. United States. doi:https://doi.org/10.17188/1665684
The Materials Project. 2020. "Materials Data on VCoO3 by Materials Project". United States. doi:https://doi.org/10.17188/1665684. https://www.osti.gov/servlets/purl/1665684. Pub date:Mon Jul 20 00:00:00 EDT 2020
@article{osti_1665684,
title = {Materials Data on VCoO3 by Materials Project},
author = {The Materials Project},
abstractNote = {CoVO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. V4+ is bonded to six equivalent O2- atoms to form VO6 octahedra that share corners with six equivalent VO6 octahedra and faces with eight equivalent CoO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All V–O bond lengths are 1.89 Å. Co2+ is bonded to twelve equivalent O2- atoms to form CoO12 cuboctahedra that share corners with twelve equivalent CoO12 cuboctahedra, faces with six equivalent CoO12 cuboctahedra, and faces with eight equivalent VO6 octahedra. All Co–O bond lengths are 2.67 Å. O2- is bonded in a distorted linear geometry to two equivalent V4+ and four equivalent Co2+ atoms.},
doi = {10.17188/1665684},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}