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Title: Materials Data on Ho5CoBi2 by Materials Project

Abstract

Ho5CoBi2 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are four inequivalent Ho sites. In the first Ho site, Ho is bonded to one Co and four equivalent Bi atoms to form a mixture of distorted corner, edge, and face-sharing HoCoBi4 trigonal bipyramids. The Ho–Co bond length is 2.69 Å. All Ho–Bi bond lengths are 3.20 Å. In the second Ho site, Ho is bonded in a 5-coordinate geometry to one Co and four equivalent Bi atoms. The Ho–Co bond length is 2.66 Å. There are two shorter (3.24 Å) and two longer (3.28 Å) Ho–Bi bond lengths. In the third Ho site, Ho is bonded in a 2-coordinate geometry to two equivalent Co and three equivalent Bi atoms. There are one shorter (2.80 Å) and one longer (2.85 Å) Ho–Co bond lengths. There are a spread of Ho–Bi bond distances ranging from 3.36–3.53 Å. In the fourth Ho site, Ho is bonded to one Co and four equivalent Bi atoms to form a mixture of distorted corner, edge, and face-sharing HoCoBi4 trigonal bipyramids. The Ho–Co bond length is 2.98 Å. There are two shorter (3.15 Å) and two longer (3.19 Å) Ho–Bi bond lengths. Comore » is bonded to seven Ho atoms to form distorted edge-sharing CoHo7 pentagonal bipyramids. Bi is bonded in a 9-coordinate geometry to nine Ho atoms.« less

Publication Date:
Other Number(s):
mp-1212341
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ho5CoBi2; Bi-Co-Ho
OSTI Identifier:
1665546
DOI:
https://doi.org/10.17188/1665546

Citation Formats

The Materials Project. Materials Data on Ho5CoBi2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1665546.
The Materials Project. Materials Data on Ho5CoBi2 by Materials Project. United States. doi:https://doi.org/10.17188/1665546
The Materials Project. 2020. "Materials Data on Ho5CoBi2 by Materials Project". United States. doi:https://doi.org/10.17188/1665546. https://www.osti.gov/servlets/purl/1665546. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1665546,
title = {Materials Data on Ho5CoBi2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ho5CoBi2 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are four inequivalent Ho sites. In the first Ho site, Ho is bonded to one Co and four equivalent Bi atoms to form a mixture of distorted corner, edge, and face-sharing HoCoBi4 trigonal bipyramids. The Ho–Co bond length is 2.69 Å. All Ho–Bi bond lengths are 3.20 Å. In the second Ho site, Ho is bonded in a 5-coordinate geometry to one Co and four equivalent Bi atoms. The Ho–Co bond length is 2.66 Å. There are two shorter (3.24 Å) and two longer (3.28 Å) Ho–Bi bond lengths. In the third Ho site, Ho is bonded in a 2-coordinate geometry to two equivalent Co and three equivalent Bi atoms. There are one shorter (2.80 Å) and one longer (2.85 Å) Ho–Co bond lengths. There are a spread of Ho–Bi bond distances ranging from 3.36–3.53 Å. In the fourth Ho site, Ho is bonded to one Co and four equivalent Bi atoms to form a mixture of distorted corner, edge, and face-sharing HoCoBi4 trigonal bipyramids. The Ho–Co bond length is 2.98 Å. There are two shorter (3.15 Å) and two longer (3.19 Å) Ho–Bi bond lengths. Co is bonded to seven Ho atoms to form distorted edge-sharing CoHo7 pentagonal bipyramids. Bi is bonded in a 9-coordinate geometry to nine Ho atoms.},
doi = {10.17188/1665546},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}