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Title: Materials Data on H12OsC4NO4F by Materials Project

Abstract

OsO4FN(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Aem2 space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four OsO4F clusters. In each OsO4F cluster, Os2- is bonded in a distorted trigonal bipyramidal geometry to four O2- and one F1- atom. There is three shorter (1.74 Å) and one longer (1.75 Å) Os–O bond length. The Os–F bond length is 2.14 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. F1- is bonded in a distorted single-bond geometry to one Os2- atom.

Publication Date:
Other Number(s):
mp-1203119
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; H12OsC4NO4F; C-F-H-N-O-Os
OSTI Identifier:
1664267
DOI:
https://doi.org/10.17188/1664267

Citation Formats

The Materials Project. Materials Data on H12OsC4NO4F by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1664267.
The Materials Project. Materials Data on H12OsC4NO4F by Materials Project. United States. doi:https://doi.org/10.17188/1664267
The Materials Project. 2020. "Materials Data on H12OsC4NO4F by Materials Project". United States. doi:https://doi.org/10.17188/1664267. https://www.osti.gov/servlets/purl/1664267. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1664267,
title = {Materials Data on H12OsC4NO4F by Materials Project},
author = {The Materials Project},
abstractNote = {OsO4FN(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Aem2 space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four OsO4F clusters. In each OsO4F cluster, Os2- is bonded in a distorted trigonal bipyramidal geometry to four O2- and one F1- atom. There is three shorter (1.74 Å) and one longer (1.75 Å) Os–O bond length. The Os–F bond length is 2.14 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one Os2- atom. F1- is bonded in a distorted single-bond geometry to one Os2- atom.},
doi = {10.17188/1664267},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}