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Title: Materials Data on V5Te8 by Materials Project

Abstract

V5Te8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are three inequivalent V+3.20+ sites. In the first V+3.20+ site, V+3.20+ is bonded to six Te2- atoms to form a mixture of edge and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 53–56°. There are a spread of V–Te bond distances ranging from 2.68–2.86 Å. In the second V+3.20+ site, V+3.20+ is bonded to six Te2- atoms to form a mixture of face, edge, and corner-sharing VTe6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are a spread of V–Te bond distances ranging from 2.65–2.82 Å. In the third V+3.20+ site, V+3.20+ is bonded to six Te2- atoms to form a mixture of face and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 53–56°. All V–Te bond lengths are 2.77 Å. There are three inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a 3-coordinate geometry to three V+3.20+ atoms. In the second Te2- site, Te2- is bonded to four V+3.20+ atoms to form a mixture of distorted edge and corner-sharing TeV4 trigonal pyramids. In the third Te2- site, Te2- is bonded to four V+3.20+ atoms to form amore » mixture of distorted edge and corner-sharing TeV4 trigonal pyramids.« less

Publication Date:
Other Number(s):
mp-1207855
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; V5Te8; Te-V
OSTI Identifier:
1663764
DOI:
https://doi.org/10.17188/1663764

Citation Formats

The Materials Project. Materials Data on V5Te8 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1663764.
The Materials Project. Materials Data on V5Te8 by Materials Project. United States. doi:https://doi.org/10.17188/1663764
The Materials Project. 2020. "Materials Data on V5Te8 by Materials Project". United States. doi:https://doi.org/10.17188/1663764. https://www.osti.gov/servlets/purl/1663764. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1663764,
title = {Materials Data on V5Te8 by Materials Project},
author = {The Materials Project},
abstractNote = {V5Te8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are three inequivalent V+3.20+ sites. In the first V+3.20+ site, V+3.20+ is bonded to six Te2- atoms to form a mixture of edge and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 53–56°. There are a spread of V–Te bond distances ranging from 2.68–2.86 Å. In the second V+3.20+ site, V+3.20+ is bonded to six Te2- atoms to form a mixture of face, edge, and corner-sharing VTe6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are a spread of V–Te bond distances ranging from 2.65–2.82 Å. In the third V+3.20+ site, V+3.20+ is bonded to six Te2- atoms to form a mixture of face and corner-sharing VTe6 octahedra. The corner-sharing octahedra tilt angles range from 53–56°. All V–Te bond lengths are 2.77 Å. There are three inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a 3-coordinate geometry to three V+3.20+ atoms. In the second Te2- site, Te2- is bonded to four V+3.20+ atoms to form a mixture of distorted edge and corner-sharing TeV4 trigonal pyramids. In the third Te2- site, Te2- is bonded to four V+3.20+ atoms to form a mixture of distorted edge and corner-sharing TeV4 trigonal pyramids.},
doi = {10.17188/1663764},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}