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Title: Materials Data on Rb2Al(H2N)2 by Materials Project

Abstract

(RbNH2)2Al crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of four aluminum molecules and one RbNH2 sheet oriented in the (0, 0, 1) direction. In the RbNH2 sheet, Rb1+ is bonded in a 3-coordinate geometry to three equivalent N+2.50- atoms. There are a spread of Rb–N bond distances ranging from 2.87–3.17 Å. N+2.50- is bonded in a water-like geometry to three equivalent Rb1+ and two H atoms. There is one shorter (1.03 Å) and one longer (1.04 Å) N–H bond length. There are two inequivalent H sites. In the first H site, H is bonded in a single-bond geometry to one N+2.50- atom. In the second H site, H is bonded in a single-bond geometry to one N+2.50- atom.

Authors:
Publication Date:
Other Number(s):
mp-1210712
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rb2Al(H2N)2; Al-H-N-Rb
OSTI Identifier:
1663061
DOI:
https://doi.org/10.17188/1663061

Citation Formats

The Materials Project. Materials Data on Rb2Al(H2N)2 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1663061.
The Materials Project. Materials Data on Rb2Al(H2N)2 by Materials Project. United States. doi:https://doi.org/10.17188/1663061
The Materials Project. 2019. "Materials Data on Rb2Al(H2N)2 by Materials Project". United States. doi:https://doi.org/10.17188/1663061. https://www.osti.gov/servlets/purl/1663061. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1663061,
title = {Materials Data on Rb2Al(H2N)2 by Materials Project},
author = {The Materials Project},
abstractNote = {(RbNH2)2Al crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of four aluminum molecules and one RbNH2 sheet oriented in the (0, 0, 1) direction. In the RbNH2 sheet, Rb1+ is bonded in a 3-coordinate geometry to three equivalent N+2.50- atoms. There are a spread of Rb–N bond distances ranging from 2.87–3.17 Å. N+2.50- is bonded in a water-like geometry to three equivalent Rb1+ and two H atoms. There is one shorter (1.03 Å) and one longer (1.04 Å) N–H bond length. There are two inequivalent H sites. In the first H site, H is bonded in a single-bond geometry to one N+2.50- atom. In the second H site, H is bonded in a single-bond geometry to one N+2.50- atom.},
doi = {10.17188/1663061},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 12 00:00:00 EST 2019},
month = {Sat Jan 12 00:00:00 EST 2019}
}