Materials Data on RhN5O7 by Materials Project

doi:10.17188/1662971

Title: Materials Data on RhN5O7 by Materials Project

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Abstract

(RhNO)2N2(NO2)6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, twelve nitrous acid molecules, and two RhNO clusters. In each RhNO cluster, Rh3+ is bonded in a distorted trigonal non-coplanar geometry to one N+2.20+ and two equivalent O2- atoms. The Rh–N bond length is 1.65 Å. There is one shorter (1.96 Å) and one longer (1.97 Å) Rh–O bond length. N+2.20+ is bonded in a single-bond geometry to one Rh3+ atom. O2- is bonded in a water-like geometry to two equivalent Rh3+ atoms.

Authors:: The Materials Project

Publication Date:: 2020-07-15

Other Number(s):: mp-1201391

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; RhN5O7; N-O-Rh

OSTI Identifier:: 1662971

DOI:: https://doi.org/10.17188/1662971

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                    The Materials Project. Materials Data on RhN5O7 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1662971.

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                    The Materials Project. Materials Data on RhN5O7 by Materials Project.  United States.  doi:https://doi.org/10.17188/1662971

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                    The Materials Project. 2020.  
"Materials Data on RhN5O7 by Materials Project".  United States.  doi:https://doi.org/10.17188/1662971.  https://www.osti.gov/servlets/purl/1662971. Pub date:Wed Jul 15 00:00:00 EDT 2020

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@article{osti_1662971,

  title        = {Materials Data on RhN5O7 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {(RhNO)2N2(NO2)6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, twelve nitrous acid molecules, and two RhNO clusters. In each RhNO cluster, Rh3+ is bonded in a distorted trigonal non-coplanar geometry to one N+2.20+ and two equivalent O2- atoms. The Rh–N bond length is 1.65 Å. There is one shorter (1.96 Å) and one longer (1.97 Å) Rh–O bond length. N+2.20+ is bonded in a single-bond geometry to one Rh3+ atom. O2- is bonded in a water-like geometry to two equivalent Rh3+ atoms.},

  doi          = {10.17188/1662971},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {7}

}

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DOI: https://doi.org/10.17188/1662971

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