DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on RhN5O7 by Materials Project

Abstract

(RhNO)2N2(NO2)6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, twelve nitrous acid molecules, and two RhNO clusters. In each RhNO cluster, Rh3+ is bonded in a distorted trigonal non-coplanar geometry to one N+2.20+ and two equivalent O2- atoms. The Rh–N bond length is 1.65 Å. There is one shorter (1.96 Å) and one longer (1.97 Å) Rh–O bond length. N+2.20+ is bonded in a single-bond geometry to one Rh3+ atom. O2- is bonded in a water-like geometry to two equivalent Rh3+ atoms.

Publication Date:
Other Number(s):
mp-1201391
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RhN5O7; N-O-Rh
OSTI Identifier:
1662971
DOI:
https://doi.org/10.17188/1662971

Citation Formats

The Materials Project. Materials Data on RhN5O7 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1662971.
The Materials Project. Materials Data on RhN5O7 by Materials Project. United States. doi:https://doi.org/10.17188/1662971
The Materials Project. 2020. "Materials Data on RhN5O7 by Materials Project". United States. doi:https://doi.org/10.17188/1662971. https://www.osti.gov/servlets/purl/1662971. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1662971,
title = {Materials Data on RhN5O7 by Materials Project},
author = {The Materials Project},
abstractNote = {(RhNO)2N2(NO2)6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia molecules, twelve nitrous acid molecules, and two RhNO clusters. In each RhNO cluster, Rh3+ is bonded in a distorted trigonal non-coplanar geometry to one N+2.20+ and two equivalent O2- atoms. The Rh–N bond length is 1.65 Å. There is one shorter (1.96 Å) and one longer (1.97 Å) Rh–O bond length. N+2.20+ is bonded in a single-bond geometry to one Rh3+ atom. O2- is bonded in a water-like geometry to two equivalent Rh3+ atoms.},
doi = {10.17188/1662971},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}