Materials Data on GeN2F5 by Materials Project

doi:10.17188/1662907

Title: Materials Data on GeN2F5 by Materials Project

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Abstract

N2(GeNF5)2 crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of two ammonia molecules and two GeNF5 sheets oriented in the (0, 0, 1) direction. In each GeNF5 sheet, Ge3+ is bonded in a distorted trigonal bipyramidal geometry to five F1- atoms. There is one shorter (1.74 Å) and four longer (1.80 Å) Ge–F bond length. N1+ is bonded in a rectangular see-saw-like geometry to four equivalent F1- atoms. All N–F bond lengths are 2.21 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Ge3+ and one N1+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Ge3+ atom.

Authors:: The Materials Project

Publication Date:: 2020-07-14

Other Number(s):: mp-1189677

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; GeN2F5; F-Ge-N

OSTI Identifier:: 1662907

DOI:: https://doi.org/10.17188/1662907

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                    The Materials Project. Materials Data on GeN2F5 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1662907.

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                    The Materials Project. Materials Data on GeN2F5 by Materials Project.  United States.  doi:https://doi.org/10.17188/1662907

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                    The Materials Project. 2020.  
"Materials Data on GeN2F5 by Materials Project".  United States.  doi:https://doi.org/10.17188/1662907.  https://www.osti.gov/servlets/purl/1662907. Pub date:Tue Jul 14 00:00:00 EDT 2020

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@article{osti_1662907,

  title        = {Materials Data on GeN2F5 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {N2(GeNF5)2 crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of two ammonia molecules and two GeNF5 sheets oriented in the (0, 0, 1) direction. In each GeNF5 sheet, Ge3+ is bonded in a distorted trigonal bipyramidal geometry to five F1- atoms. There is one shorter (1.74 Å) and four longer (1.80 Å) Ge–F bond length. N1+ is bonded in a rectangular see-saw-like geometry to four equivalent F1- atoms. All N–F bond lengths are 2.21 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Ge3+ and one N1+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Ge3+ atom.},

  doi          = {10.17188/1662907},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {7}

}

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DOI: https://doi.org/10.17188/1662907

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