U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Pt(IN)2 by Materials Project
Abstract
Pt(NI)2 crystallizes in the tetragonal P4/mnc space group. The structure is one-dimensional and consists of two Pt(NI)2 ribbons oriented in the (0, 0, 1) direction. there are two inequivalent Pt2+ sites. In the first Pt2+ site, Pt2+ is bonded to two equivalent Pt2+ and four equivalent I1- atoms to form corner-sharing PtPt2I4 octahedra. The corner-sharing octahedral tilt angles are 0°. Both Pt–Pt bond lengths are 2.48 Å. All Pt–I bond lengths are 2.64 Å. In the second Pt2+ site, Pt2+ is bonded in a square co-planar geometry to two equivalent Pt2+ and four equivalent N atoms. All Pt–N bond lengths are 2.04 Å. N is bonded in a 1-coordinate geometry to one Pt2+ and two equivalent I1- atoms. Both N–I bond lengths are 2.55 Å. I1- is bonded in a distorted T-shaped geometry to one Pt2+ and two equivalent N atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1209519
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Pt(IN)2; I-N-Pt
- OSTI Identifier:
- 1662341
- DOI:
- https://doi.org/10.17188/1662341
Citation Formats
The Materials Project. Materials Data on Pt(IN)2 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1662341.
The Materials Project. Materials Data on Pt(IN)2 by Materials Project. United States. doi:https://doi.org/10.17188/1662341
The Materials Project. 2019.
"Materials Data on Pt(IN)2 by Materials Project". United States. doi:https://doi.org/10.17188/1662341. https://www.osti.gov/servlets/purl/1662341. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1662341,
title = {Materials Data on Pt(IN)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Pt(NI)2 crystallizes in the tetragonal P4/mnc space group. The structure is one-dimensional and consists of two Pt(NI)2 ribbons oriented in the (0, 0, 1) direction. there are two inequivalent Pt2+ sites. In the first Pt2+ site, Pt2+ is bonded to two equivalent Pt2+ and four equivalent I1- atoms to form corner-sharing PtPt2I4 octahedra. The corner-sharing octahedral tilt angles are 0°. Both Pt–Pt bond lengths are 2.48 Å. All Pt–I bond lengths are 2.64 Å. In the second Pt2+ site, Pt2+ is bonded in a square co-planar geometry to two equivalent Pt2+ and four equivalent N atoms. All Pt–N bond lengths are 2.04 Å. N is bonded in a 1-coordinate geometry to one Pt2+ and two equivalent I1- atoms. Both N–I bond lengths are 2.55 Å. I1- is bonded in a distorted T-shaped geometry to one Pt2+ and two equivalent N atoms.},
doi = {10.17188/1662341},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}