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Title: Materials Data on AgClO4 by Materials Project

Abstract

AgClO4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ag is bonded to six O atoms to form distorted AgO6 octahedra that share corners with six equivalent ClO4 tetrahedra and edges with two equivalent AgO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.55–2.71 Å. There are three inequivalent O sites. In the first O site, O is bonded in a 3-coordinate geometry to two equivalent Ag and one Cl atom. The O–Cl bond length is 1.48 Å. In the second O site, O is bonded in a distorted bent 120 degrees geometry to one Ag and one Cl atom. The O–Cl bond length is 1.46 Å. In the third O site, O is bonded in a distorted bent 150 degrees geometry to one Ag and one Cl atom. The O–Cl bond length is 1.45 Å. Cl is bonded to four O atoms to form ClO4 tetrahedra that share corners with six equivalent AgO6 octahedra. The corner-sharing octahedra tilt angles range from 20–68°.

Publication Date:
Other Number(s):
mp-1191267
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AgClO4; Ag-Cl-O
OSTI Identifier:
1656176
DOI:
https://doi.org/10.17188/1656176

Citation Formats

The Materials Project. Materials Data on AgClO4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1656176.
The Materials Project. Materials Data on AgClO4 by Materials Project. United States. doi:https://doi.org/10.17188/1656176
The Materials Project. 2020. "Materials Data on AgClO4 by Materials Project". United States. doi:https://doi.org/10.17188/1656176. https://www.osti.gov/servlets/purl/1656176. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1656176,
title = {Materials Data on AgClO4 by Materials Project},
author = {The Materials Project},
abstractNote = {AgClO4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ag is bonded to six O atoms to form distorted AgO6 octahedra that share corners with six equivalent ClO4 tetrahedra and edges with two equivalent AgO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.55–2.71 Å. There are three inequivalent O sites. In the first O site, O is bonded in a 3-coordinate geometry to two equivalent Ag and one Cl atom. The O–Cl bond length is 1.48 Å. In the second O site, O is bonded in a distorted bent 120 degrees geometry to one Ag and one Cl atom. The O–Cl bond length is 1.46 Å. In the third O site, O is bonded in a distorted bent 150 degrees geometry to one Ag and one Cl atom. The O–Cl bond length is 1.45 Å. Cl is bonded to four O atoms to form ClO4 tetrahedra that share corners with six equivalent AgO6 octahedra. The corner-sharing octahedra tilt angles range from 20–68°.},
doi = {10.17188/1656176},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}