Materials Data on Bi2O3 by Materials Project

doi:10.17188/1651877

Title: Materials Data on Bi2O3 by Materials Project

Abstract

Bi2O3 is Corundum-like structured and crystallizes in the cubic Ia-3 space group. The structure is three-dimensional. there are two inequivalent Bi3+ sites. In the first Bi3+ site, Bi3+ is bonded to six equivalent O2- atoms to form a mixture of edge and corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Bi–O bond lengths are 2.43 Å. In the second Bi3+ site, Bi3+ is bonded to six equivalent O2- atoms to form a mixture of distorted edge and corner-sharing BiO6 octahedra. The corner-sharing octahedra tilt angles range from 54–56°. There are a spread of Bi–O bond distances ranging from 2.31–2.56 Å. O2- is bonded to four Bi3+ atoms to form a mixture of distorted edge and corner-sharing OBi4 trigonal pyramids.

Authors:: The Materials Project

Publication Date:: Wed Apr 29 00:00:00 EDT 2020

Other Number(s):: mp-1204405

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Bi2O3; Bi-O

OSTI Identifier:: 1651877

DOI:: https://doi.org/10.17188/1651877

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                    The Materials Project. Materials Data on Bi2O3 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1651877.

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                    The Materials Project. Materials Data on Bi2O3 by Materials Project.  United States.  doi:https://doi.org/10.17188/1651877

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                    The Materials Project. 2020.  
"Materials Data on Bi2O3 by Materials Project".  United States.  doi:https://doi.org/10.17188/1651877.  https://www.osti.gov/servlets/purl/1651877. Pub date:Wed Apr 29 00:00:00 EDT 2020

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@article{osti_1651877,

  title        = {Materials Data on Bi2O3 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Bi2O3 is Corundum-like structured and crystallizes in the cubic Ia-3 space group. The structure is three-dimensional. there are two inequivalent Bi3+ sites. In the first Bi3+ site, Bi3+ is bonded to six equivalent O2- atoms to form a mixture of edge and corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Bi–O bond lengths are 2.43 Å. In the second Bi3+ site, Bi3+ is bonded to six equivalent O2- atoms to form a mixture of distorted edge and corner-sharing BiO6 octahedra. The corner-sharing octahedra tilt angles range from 54–56°. There are a spread of Bi–O bond distances ranging from 2.31–2.56 Å. O2- is bonded to four Bi3+ atoms to form a mixture of distorted edge and corner-sharing OBi4 trigonal pyramids.},

  doi          = {10.17188/1651877},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Wed Apr 29 00:00:00 EDT 2020},

  month        = {Wed Apr 29 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1651877

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Works referenced in this record:

Synthesis and properties of glasses in the K2O–SiO2–Bi2O3–TiO2 system and bismuth titanate (Bi4Ti3O12) nano glass–ceramics thereof
journal, December 2010

Molla, Atiar Rahaman; Tarafder, Anal; Karmakar, Basudeb
Journal of Materials Science, Vol. 46, Issue 9
https://doi.org/10.1007/s10853-010-5173-1

Electrochemical reaction of lithium with orthorhombic bismuth tungstate thin films fabricated by radio-frequency sputtering
journal, December 2009

Li, Chi-Lin; Sun, Ke; Yu, Le
Electrochimica Acta, Vol. 55, Issue 1
https://doi.org/10.1016/j.electacta.2009.04.037

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Materials Data on Bi2O3 by Materials Project

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Similar Records

Title: Materials Data on Bi2O3 by Materials Project

Abstract

Citation Formats

Synthesis and properties of glasses in the K2O–SiO2–Bi2O3–TiO2 system and bismuth titanate (Bi4Ti3O12) nano glass–ceramics thereof journal, December 2010

Electrochemical reaction of lithium with orthorhombic bismuth tungstate thin films fabricated by radio-frequency sputtering journal, December 2009

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journal, December 2010

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journal, December 2009