U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Tb3Sn7 by Materials Project
Abstract
Tb3Sn7 crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded to twelve Sn atoms to form a mixture of corner and face-sharing TbSn12 cuboctahedra. There are four shorter (3.18 Å) and eight longer (3.37 Å) Tb–Sn bond lengths. In the second Tb site, Tb is bonded in a 10-coordinate geometry to ten Sn atoms. There are a spread of Tb–Sn bond distances ranging from 3.24–3.45 Å. There are four inequivalent Sn sites. In the first Sn site, Sn is bonded in a square co-planar geometry to four equivalent Tb and eight Sn atoms. All Sn–Sn bond lengths are 3.37 Å. In the second Sn site, Sn is bonded in a 10-coordinate geometry to four Tb and six Sn atoms. All Sn–Sn bond lengths are 3.18 Å. In the third Sn site, Sn is bonded in a 10-coordinate geometry to four Tb and six Sn atoms. In the fourth Sn site, Sn is bonded in a 8-coordinate geometry to six equivalent Tb and two equivalent Sn atoms. Both Sn–Sn bond lengths are 3.02 Å.
- Publication Date:
- Other Number(s):
- mp-1079704
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Sn-Tb; Tb3Sn7; crystal structure
- OSTI Identifier:
- 1651658
- DOI:
- https://doi.org/10.17188/1651658
Citation Formats
Materials Data on Tb3Sn7 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1651658.
Materials Data on Tb3Sn7 by Materials Project. United States. doi:https://doi.org/10.17188/1651658
2020.
"Materials Data on Tb3Sn7 by Materials Project". United States. doi:https://doi.org/10.17188/1651658. https://www.osti.gov/servlets/purl/1651658. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1651658,
title = {Materials Data on Tb3Sn7 by Materials Project},
abstractNote = {Tb3Sn7 crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded to twelve Sn atoms to form a mixture of corner and face-sharing TbSn12 cuboctahedra. There are four shorter (3.18 Å) and eight longer (3.37 Å) Tb–Sn bond lengths. In the second Tb site, Tb is bonded in a 10-coordinate geometry to ten Sn atoms. There are a spread of Tb–Sn bond distances ranging from 3.24–3.45 Å. There are four inequivalent Sn sites. In the first Sn site, Sn is bonded in a square co-planar geometry to four equivalent Tb and eight Sn atoms. All Sn–Sn bond lengths are 3.37 Å. In the second Sn site, Sn is bonded in a 10-coordinate geometry to four Tb and six Sn atoms. All Sn–Sn bond lengths are 3.18 Å. In the third Sn site, Sn is bonded in a 10-coordinate geometry to four Tb and six Sn atoms. In the fourth Sn site, Sn is bonded in a 8-coordinate geometry to six equivalent Tb and two equivalent Sn atoms. Both Sn–Sn bond lengths are 3.02 Å.},
doi = {10.17188/1651658},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}