U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sn4SF6 by Materials Project
Abstract
Sn4SF6 crystallizes in the trigonal R3 space group. The structure is three-dimensional. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded in a 2-coordinate geometry to one S2- and three F1- atoms. The Sn–S bond length is 2.68 Å. There are a spread of Sn–F bond distances ranging from 2.14–2.70 Å. In the second Sn2+ site, Sn2+ is bonded in a 6-coordinate geometry to six F1- atoms. There are three shorter (2.21 Å) and three longer (2.64 Å) Sn–F bond lengths. S2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sn2+ atoms. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to three Sn2+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two Sn2+ atoms.
- Publication Date:
- Other Number(s):
- mp-1021490
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-S-Sn; Sn4SF6; crystal structure
- OSTI Identifier:
- 1351417
- DOI:
- https://doi.org/10.17188/1351417
Citation Formats
Materials Data on Sn4SF6 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1351417.
Materials Data on Sn4SF6 by Materials Project. United States. doi:https://doi.org/10.17188/1351417
2020.
"Materials Data on Sn4SF6 by Materials Project". United States. doi:https://doi.org/10.17188/1351417. https://www.osti.gov/servlets/purl/1351417. Pub date:Wed Jul 22 00:00:00 EDT 2020
@article{osti_1351417,
title = {Materials Data on Sn4SF6 by Materials Project},
abstractNote = {Sn4SF6 crystallizes in the trigonal R3 space group. The structure is three-dimensional. there are two inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded in a 2-coordinate geometry to one S2- and three F1- atoms. The Sn–S bond length is 2.68 Å. There are a spread of Sn–F bond distances ranging from 2.14–2.70 Å. In the second Sn2+ site, Sn2+ is bonded in a 6-coordinate geometry to six F1- atoms. There are three shorter (2.21 Å) and three longer (2.64 Å) Sn–F bond lengths. S2- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sn2+ atoms. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to three Sn2+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two Sn2+ atoms.},
doi = {10.17188/1351417},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}