skip to main content
DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on KCdSb by Materials Project

Abstract

KCdSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. K1+ is bonded to five equivalent Sb3- atoms to form distorted KSb5 trigonal bipyramids that share corners with twelve equivalent CdSb4 tetrahedra, corners with four equivalent KSb5 trigonal bipyramids, edges with four equivalent CdSb4 tetrahedra, and edges with eight equivalent KSb5 trigonal bipyramids. There are four shorter (3.60 Å) and one longer (3.75 Å) K–Sb bond lengths. Cd2+ is bonded to four equivalent Sb3- atoms to form CdSb4 tetrahedra that share corners with four equivalent CdSb4 tetrahedra, corners with twelve equivalent KSb5 trigonal bipyramids, edges with four equivalent CdSb4 tetrahedra, and edges with four equivalent KSb5 trigonal bipyramids. All Cd–Sb bond lengths are 3.01 Å. Sb3- is bonded in a 9-coordinate geometry to five equivalent K1+ and four equivalent Cd2+ atoms.

Publication Date:
Other Number(s):
mp-1018652
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; KCdSb; Cd-K-Sb
OSTI Identifier:
1350334
DOI:
10.17188/1350334

Citation Formats

The Materials Project. Materials Data on KCdSb by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1350334.
The Materials Project. Materials Data on KCdSb by Materials Project. United States. doi:10.17188/1350334.
The Materials Project. 2020. "Materials Data on KCdSb by Materials Project". United States. doi:10.17188/1350334. https://www.osti.gov/servlets/purl/1350334. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1350334,
title = {Materials Data on KCdSb by Materials Project},
author = {The Materials Project},
abstractNote = {KCdSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. K1+ is bonded to five equivalent Sb3- atoms to form distorted KSb5 trigonal bipyramids that share corners with twelve equivalent CdSb4 tetrahedra, corners with four equivalent KSb5 trigonal bipyramids, edges with four equivalent CdSb4 tetrahedra, and edges with eight equivalent KSb5 trigonal bipyramids. There are four shorter (3.60 Å) and one longer (3.75 Å) K–Sb bond lengths. Cd2+ is bonded to four equivalent Sb3- atoms to form CdSb4 tetrahedra that share corners with four equivalent CdSb4 tetrahedra, corners with twelve equivalent KSb5 trigonal bipyramids, edges with four equivalent CdSb4 tetrahedra, and edges with four equivalent KSb5 trigonal bipyramids. All Cd–Sb bond lengths are 3.01 Å. Sb3- is bonded in a 9-coordinate geometry to five equivalent K1+ and four equivalent Cd2+ atoms.},
doi = {10.17188/1350334},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

Dataset:

Save / Share: