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Title: Materials Data on Zn(MoO2)2 by Materials Project

Abstract

Zn(MoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Mo3+ is bonded to six equivalent O2- atoms to form MoO6 octahedra that share corners with six equivalent ZnO4 tetrahedra and edges with six equivalent MoO6 octahedra. There are four shorter (2.18 Å) and two longer (2.19 Å) Mo–O bond lengths. Zn2+ is bonded to four equivalent O2- atoms to form ZnO4 tetrahedra that share corners with twelve equivalent MoO6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Zn–O bond lengths are 2.05 Å. O2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Mo3+ and one Zn2+ atom.

Authors:
Publication Date:
Other Number(s):
mvc-4829
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Zn(MoO2)2; Mo-O-Zn
OSTI Identifier:
1321142
DOI:
https://doi.org/10.17188/1321142

Citation Formats

The Materials Project. Materials Data on Zn(MoO2)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1321142.
The Materials Project. Materials Data on Zn(MoO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1321142
The Materials Project. 2020. "Materials Data on Zn(MoO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1321142. https://www.osti.gov/servlets/purl/1321142. Pub date:Mon Aug 03 00:00:00 EDT 2020
@article{osti_1321142,
title = {Materials Data on Zn(MoO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Zn(MoO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Mo3+ is bonded to six equivalent O2- atoms to form MoO6 octahedra that share corners with six equivalent ZnO4 tetrahedra and edges with six equivalent MoO6 octahedra. There are four shorter (2.18 Å) and two longer (2.19 Å) Mo–O bond lengths. Zn2+ is bonded to four equivalent O2- atoms to form ZnO4 tetrahedra that share corners with twelve equivalent MoO6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Zn–O bond lengths are 2.05 Å. O2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Mo3+ and one Zn2+ atom.},
doi = {10.17188/1321142},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}