DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Ca3Co2(GeO4)3 by Materials Project

Abstract

Ca3Co2(GeO4)3 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Ca2+ is bonded in a distorted body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.40 Å) and four longer (2.53 Å) Ca–O bond lengths. Co3+ is bonded to six equivalent O2- atoms to form CoO6 octahedra that share corners with six equivalent GeO4 tetrahedra. All Co–O bond lengths are 2.03 Å. Ge4+ is bonded to four equivalent O2- atoms to form GeO4 tetrahedra that share corners with four equivalent CoO6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Ge–O bond lengths are 1.79 Å. O2- is bonded in a 4-coordinate geometry to two equivalent Ca2+, one Co3+, and one Ge4+ atom.

Authors:
Publication Date:
Other Number(s):
mvc-4409
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ca3Co2(GeO4)3; Ca-Co-Ge-O
OSTI Identifier:
1320999
DOI:
https://doi.org/10.17188/1320999

Citation Formats

The Materials Project. Materials Data on Ca3Co2(GeO4)3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1320999.
The Materials Project. Materials Data on Ca3Co2(GeO4)3 by Materials Project. United States. doi:https://doi.org/10.17188/1320999
The Materials Project. 2020. "Materials Data on Ca3Co2(GeO4)3 by Materials Project". United States. doi:https://doi.org/10.17188/1320999. https://www.osti.gov/servlets/purl/1320999. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1320999,
title = {Materials Data on Ca3Co2(GeO4)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Ca3Co2(GeO4)3 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Ca2+ is bonded in a distorted body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.40 Å) and four longer (2.53 Å) Ca–O bond lengths. Co3+ is bonded to six equivalent O2- atoms to form CoO6 octahedra that share corners with six equivalent GeO4 tetrahedra. All Co–O bond lengths are 2.03 Å. Ge4+ is bonded to four equivalent O2- atoms to form GeO4 tetrahedra that share corners with four equivalent CoO6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Ge–O bond lengths are 1.79 Å. O2- is bonded in a 4-coordinate geometry to two equivalent Ca2+, one Co3+, and one Ge4+ atom.},
doi = {10.17188/1320999},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}