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Title: Materials Data on Mn2Zn2O5 by Materials Project

Abstract

Mn2Zn2O5 is Aluminum carbonitride-like structured and crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. Mn3+ is bonded to five O2- atoms to form distorted corner-sharing MnO5 trigonal bipyramids. There are a spread of Mn–O bond distances ranging from 1.88–2.08 Å. Zn2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Zn–O bond distances ranging from 2.05–2.56 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted linear geometry to two equivalent Mn3+ and four equivalent Zn2+ atoms. In the second O2- site, O2- is bonded to two equivalent Mn3+ and two equivalent Zn2+ atoms to form a mixture of edge and corner-sharing OMn2Zn2 tetrahedra. In the third O2- site, O2- is bonded to two equivalent Mn3+ and two equivalent Zn2+ atoms to form a mixture of distorted edge and corner-sharing OMn2Zn2 trigonal pyramids.

Authors:
Publication Date:
Other Number(s):
mvc-3981
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Mn2Zn2O5; Mn-O-Zn
OSTI Identifier:
1320805
DOI:
https://doi.org/10.17188/1320805

Citation Formats

The Materials Project. Materials Data on Mn2Zn2O5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1320805.
The Materials Project. Materials Data on Mn2Zn2O5 by Materials Project. United States. doi:https://doi.org/10.17188/1320805
The Materials Project. 2020. "Materials Data on Mn2Zn2O5 by Materials Project". United States. doi:https://doi.org/10.17188/1320805. https://www.osti.gov/servlets/purl/1320805. Pub date:Mon Aug 03 00:00:00 EDT 2020
@article{osti_1320805,
title = {Materials Data on Mn2Zn2O5 by Materials Project},
author = {The Materials Project},
abstractNote = {Mn2Zn2O5 is Aluminum carbonitride-like structured and crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. Mn3+ is bonded to five O2- atoms to form distorted corner-sharing MnO5 trigonal bipyramids. There are a spread of Mn–O bond distances ranging from 1.88–2.08 Å. Zn2+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Zn–O bond distances ranging from 2.05–2.56 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted linear geometry to two equivalent Mn3+ and four equivalent Zn2+ atoms. In the second O2- site, O2- is bonded to two equivalent Mn3+ and two equivalent Zn2+ atoms to form a mixture of edge and corner-sharing OMn2Zn2 tetrahedra. In the third O2- site, O2- is bonded to two equivalent Mn3+ and two equivalent Zn2+ atoms to form a mixture of distorted edge and corner-sharing OMn2Zn2 trigonal pyramids.},
doi = {10.17188/1320805},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {8}
}