U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on ZnCoF4 by Materials Project
Abstract
CoZnF4 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are two inequivalent Co2+ sites. In the first Co2+ site, Co2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Co–F bond distances ranging from 2.09–2.34 Å. In the second Co2+ site, Co2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Co–F bond distances ranging from 2.08–2.34 Å. There are two inequivalent Zn2+ sites. In the first Zn2+ site, Zn2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Zn–F bond distances ranging from 2.10–2.29 Å. In the second Zn2+ site, Zn2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Zn–F bond distances ranging from 2.13–2.31 Å. There are eight inequivalent F1- sites. In the first F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of distorted corner and edge-sharing FZn2Co2 tetrahedra. In the second F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of corner and edge-sharing FZn2Co2 tetrahedra. In the thirdmore »
- Authors:
- Publication Date:
- Other Number(s):
- mvc-3380
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; ZnCoF4; Co-F-Zn
- OSTI Identifier:
- 1320541
- DOI:
- https://doi.org/10.17188/1320541
Citation Formats
The Materials Project. Materials Data on ZnCoF4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1320541.
The Materials Project. Materials Data on ZnCoF4 by Materials Project. United States. doi:https://doi.org/10.17188/1320541
The Materials Project. 2020.
"Materials Data on ZnCoF4 by Materials Project". United States. doi:https://doi.org/10.17188/1320541. https://www.osti.gov/servlets/purl/1320541. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1320541,
title = {Materials Data on ZnCoF4 by Materials Project},
author = {The Materials Project},
abstractNote = {CoZnF4 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are two inequivalent Co2+ sites. In the first Co2+ site, Co2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Co–F bond distances ranging from 2.09–2.34 Å. In the second Co2+ site, Co2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Co–F bond distances ranging from 2.08–2.34 Å. There are two inequivalent Zn2+ sites. In the first Zn2+ site, Zn2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Zn–F bond distances ranging from 2.10–2.29 Å. In the second Zn2+ site, Zn2+ is bonded in a body-centered cubic geometry to eight F1- atoms. There are a spread of Zn–F bond distances ranging from 2.13–2.31 Å. There are eight inequivalent F1- sites. In the first F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of distorted corner and edge-sharing FZn2Co2 tetrahedra. In the second F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of corner and edge-sharing FZn2Co2 tetrahedra. In the third F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of distorted corner and edge-sharing FZn2Co2 tetrahedra. In the fourth F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of corner and edge-sharing FZn2Co2 tetrahedra. In the fifth F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of corner and edge-sharing FZn2Co2 tetrahedra. In the sixth F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of distorted corner and edge-sharing FZn2Co2 tetrahedra. In the seventh F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of corner and edge-sharing FZn2Co2 tetrahedra. In the eighth F1- site, F1- is bonded to two Co2+ and two Zn2+ atoms to form a mixture of distorted corner and edge-sharing FZn2Co2 tetrahedra.},
doi = {10.17188/1320541},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jul 18 00:00:00 EDT 2020},
month = {Sat Jul 18 00:00:00 EDT 2020}
}