Materials Data on SbF5 by Materials Project

doi:10.17188/1319005

Title: Materials Data on SbF5 by Materials Project

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Abstract

SbF5 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two SbF5 sheets oriented in the (0, 0, 1) direction. Sb5+ is bonded to eight F1- atoms to form a mixture of distorted edge and corner-sharing SbF8 hexagonal bipyramids. There are a spread of Sb–F bond distances ranging from 1.88–2.29 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Sb5+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a distorted linear geometry to two equivalent Sb5+ atoms.

Authors:: The Materials Project

Publication Date:: 2020-07-18

Other Number(s):: mvc-13958

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; SbF5; F-Sb

OSTI Identifier:: 1319005

DOI:: https://doi.org/10.17188/1319005

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                    The Materials Project. Materials Data on SbF5 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1319005.

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                    The Materials Project. Materials Data on SbF5 by Materials Project.  United States.  doi:https://doi.org/10.17188/1319005

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                    The Materials Project. 2020.  
"Materials Data on SbF5 by Materials Project".  United States.  doi:https://doi.org/10.17188/1319005.  https://www.osti.gov/servlets/purl/1319005. Pub date:Sat Jul 18 00:00:00 EDT 2020

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@article{osti_1319005,

  title        = {Materials Data on SbF5 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {SbF5 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two SbF5 sheets oriented in the (0, 0, 1) direction. Sb5+ is bonded to eight F1- atoms to form a mixture of distorted edge and corner-sharing SbF8 hexagonal bipyramids. There are a spread of Sb–F bond distances ranging from 1.88–2.29 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Sb5+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a distorted linear geometry to two equivalent Sb5+ atoms.},

  doi          = {10.17188/1319005},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {7}

}

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DOI: https://doi.org/10.17188/1319005

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