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Title: Materials Data on BiF5 by Materials Project

Abstract

BiF5 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two BiF5 sheets oriented in the (0, 0, 1) direction. Bi5+ is bonded to eight F1- atoms to form a mixture of edge and corner-sharing BiF8 hexagonal bipyramids. There are a spread of Bi–F bond distances ranging from 2.02–2.38 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Bi5+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Bi5+ atom. In the third F1- site, F1- is bonded in a distorted linear geometry to two equivalent Bi5+ atoms.

Publication Date:
Other Number(s):
mvc-13496
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; BiF5; Bi-F
OSTI Identifier:
1318901
DOI:
https://doi.org/10.17188/1318901

Citation Formats

The Materials Project. Materials Data on BiF5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1318901.
The Materials Project. Materials Data on BiF5 by Materials Project. United States. doi:https://doi.org/10.17188/1318901
The Materials Project. 2020. "Materials Data on BiF5 by Materials Project". United States. doi:https://doi.org/10.17188/1318901. https://www.osti.gov/servlets/purl/1318901. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1318901,
title = {Materials Data on BiF5 by Materials Project},
author = {The Materials Project},
abstractNote = {BiF5 crystallizes in the orthorhombic Immm space group. The structure is two-dimensional and consists of two BiF5 sheets oriented in the (0, 0, 1) direction. Bi5+ is bonded to eight F1- atoms to form a mixture of edge and corner-sharing BiF8 hexagonal bipyramids. There are a spread of Bi–F bond distances ranging from 2.02–2.38 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Bi5+ atoms. In the second F1- site, F1- is bonded in a single-bond geometry to one Bi5+ atom. In the third F1- site, F1- is bonded in a distorted linear geometry to two equivalent Bi5+ atoms.},
doi = {10.17188/1318901},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}