U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on LiSnCl3 by Materials Project
Abstract
LiSnCl3 crystallizes in the trigonal R3c space group. The structure is three-dimensional. Li1+ is bonded to six equivalent Cl1- atoms to form LiCl6 octahedra that share corners with three equivalent SnCl6 octahedra, corners with six equivalent LiCl6 octahedra, edges with three equivalent SnCl6 octahedra, and a faceface with one SnCl6 octahedra. The corner-sharing octahedra tilt angles range from 32–65°. There are three shorter (2.51 Å) and three longer (2.76 Å) Li–Cl bond lengths. Sn2+ is bonded to six equivalent Cl1- atoms to form distorted SnCl6 octahedra that share corners with three equivalent LiCl6 octahedra, corners with six equivalent SnCl6 octahedra, edges with three equivalent LiCl6 octahedra, and a faceface with one LiCl6 octahedra. The corner-sharing octahedra tilt angles range from 59–65°. There are three shorter (2.69 Å) and three longer (3.13 Å) Sn–Cl bond lengths. Cl1- is bonded in a 4-coordinate geometry to two equivalent Li1+ and two equivalent Sn2+ atoms.
- Publication Date:
- Other Number(s):
- mp-998591
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cl-Li-Sn; LiSnCl3; crystal structure
- OSTI Identifier:
- 1317355
- DOI:
- https://doi.org/10.17188/1317355
Citation Formats
Materials Data on LiSnCl3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1317355.
Materials Data on LiSnCl3 by Materials Project. United States. doi:https://doi.org/10.17188/1317355
2020.
"Materials Data on LiSnCl3 by Materials Project". United States. doi:https://doi.org/10.17188/1317355. https://www.osti.gov/servlets/purl/1317355. Pub date:Mon May 04 04:00:00 UTC 2020
@article{osti_1317355,
title = {Materials Data on LiSnCl3 by Materials Project},
abstractNote = {LiSnCl3 crystallizes in the trigonal R3c space group. The structure is three-dimensional. Li1+ is bonded to six equivalent Cl1- atoms to form LiCl6 octahedra that share corners with three equivalent SnCl6 octahedra, corners with six equivalent LiCl6 octahedra, edges with three equivalent SnCl6 octahedra, and a faceface with one SnCl6 octahedra. The corner-sharing octahedra tilt angles range from 32–65°. There are three shorter (2.51 Å) and three longer (2.76 Å) Li–Cl bond lengths. Sn2+ is bonded to six equivalent Cl1- atoms to form distorted SnCl6 octahedra that share corners with three equivalent LiCl6 octahedra, corners with six equivalent SnCl6 octahedra, edges with three equivalent LiCl6 octahedra, and a faceface with one LiCl6 octahedra. The corner-sharing octahedra tilt angles range from 59–65°. There are three shorter (2.69 Å) and three longer (3.13 Å) Sn–Cl bond lengths. Cl1- is bonded in a 4-coordinate geometry to two equivalent Li1+ and two equivalent Sn2+ atoms.},
doi = {10.17188/1317355},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}