U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on ZnAgF3 by Materials Project
Abstract
AgZnF3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Ag1+ is bonded to six equivalent F1- atoms to form distorted AgF6 octahedra that share corners with nine equivalent ZnF6 octahedra, edges with three equivalent AgF6 octahedra, and a faceface with one ZnF6 octahedra. The corner-sharing octahedra tilt angles range from 38–60°. There are three shorter (2.44 Å) and three longer (2.62 Å) Ag–F bond lengths. Zn2+ is bonded to six equivalent F1- atoms to form ZnF6 octahedra that share corners with nine equivalent AgF6 octahedra, edges with three equivalent ZnF6 octahedra, and a faceface with one AgF6 octahedra. The corner-sharing octahedra tilt angles range from 38–60°. There are three shorter (2.05 Å) and three longer (2.11 Å) Zn–F bond lengths. F1- is bonded in a 4-coordinate geometry to two equivalent Ag1+ and two equivalent Zn2+ atoms.
- Publication Date:
- Other Number(s):
- mp-998537
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Ag-F-Zn; ZnAgF3; crystal structure
- OSTI Identifier:
- 1317344
- DOI:
- https://doi.org/10.17188/1317344
Citation Formats
Materials Data on ZnAgF3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1317344.
Materials Data on ZnAgF3 by Materials Project. United States. doi:https://doi.org/10.17188/1317344
2020.
"Materials Data on ZnAgF3 by Materials Project". United States. doi:https://doi.org/10.17188/1317344. https://www.osti.gov/servlets/purl/1317344. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1317344,
title = {Materials Data on ZnAgF3 by Materials Project},
abstractNote = {AgZnF3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Ag1+ is bonded to six equivalent F1- atoms to form distorted AgF6 octahedra that share corners with nine equivalent ZnF6 octahedra, edges with three equivalent AgF6 octahedra, and a faceface with one ZnF6 octahedra. The corner-sharing octahedra tilt angles range from 38–60°. There are three shorter (2.44 Å) and three longer (2.62 Å) Ag–F bond lengths. Zn2+ is bonded to six equivalent F1- atoms to form ZnF6 octahedra that share corners with nine equivalent AgF6 octahedra, edges with three equivalent ZnF6 octahedra, and a faceface with one AgF6 octahedra. The corner-sharing octahedra tilt angles range from 38–60°. There are three shorter (2.05 Å) and three longer (2.11 Å) Zn–F bond lengths. F1- is bonded in a 4-coordinate geometry to two equivalent Ag1+ and two equivalent Zn2+ atoms.},
doi = {10.17188/1317344},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}