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Title: Materials Data on RbSnF3 by Materials Project

Abstract

RbSnF3 crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of one RbSnF3 sheet oriented in the (0, 0, 1) direction. Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.93–3.37 Å. Sn2+ is bonded to five F1- atoms to form distorted corner-sharing SnF5 square pyramids. There are a spread of Sn–F bond distances ranging from 2.10–2.52 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Sn2+ atoms. In the second F1- site, F1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Sn2+ atom. In the third F1- site, F1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Sn2+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-998193
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbSnF3; F-Rb-Sn
OSTI Identifier:
1317280
DOI:
https://doi.org/10.17188/1317280

Citation Formats

The Materials Project. Materials Data on RbSnF3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1317280.
The Materials Project. Materials Data on RbSnF3 by Materials Project. United States. doi:https://doi.org/10.17188/1317280
The Materials Project. 2020. "Materials Data on RbSnF3 by Materials Project". United States. doi:https://doi.org/10.17188/1317280. https://www.osti.gov/servlets/purl/1317280. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1317280,
title = {Materials Data on RbSnF3 by Materials Project},
author = {The Materials Project},
abstractNote = {RbSnF3 crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of one RbSnF3 sheet oriented in the (0, 0, 1) direction. Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.93–3.37 Å. Sn2+ is bonded to five F1- atoms to form distorted corner-sharing SnF5 square pyramids. There are a spread of Sn–F bond distances ranging from 2.10–2.52 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Sn2+ atoms. In the second F1- site, F1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Sn2+ atom. In the third F1- site, F1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Sn2+ atoms.},
doi = {10.17188/1317280},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}