U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on RbPd2F5 by Materials Project
Abstract
RbPd2F5 crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. Rb1+ is bonded in a 11-coordinate geometry to eleven F1- atoms. There are a spread of Rb–F bond distances ranging from 2.94–3.29 Å. There are two inequivalent Pd2+ sites. In the first Pd2+ site, Pd2+ is bonded to six F1- atoms to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles are 55°. All Pd–F bond lengths are 2.20 Å. In the second Pd2+ site, Pd2+ is bonded in a square co-planar geometry to four equivalent F1- atoms. All Pd–F bond lengths are 2.00 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 2-coordinate geometry to two equivalent Rb1+ and two Pd2+ atoms. In the second F1- site, F1- is bonded in a 2-coordinate geometry to three equivalent Rb1+ and two equivalent Pd2+ atoms.
- Publication Date:
- Other Number(s):
- mp-8958
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-Pd-Rb; RbPd2F5; crystal structure
- OSTI Identifier:
- 1312863
- DOI:
- https://doi.org/10.17188/1312863
Citation Formats
Materials Data on RbPd2F5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1312863.
Materials Data on RbPd2F5 by Materials Project. United States. doi:https://doi.org/10.17188/1312863
2020.
"Materials Data on RbPd2F5 by Materials Project". United States. doi:https://doi.org/10.17188/1312863. https://www.osti.gov/servlets/purl/1312863. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1312863,
title = {Materials Data on RbPd2F5 by Materials Project},
abstractNote = {RbPd2F5 crystallizes in the orthorhombic Imma space group. The structure is three-dimensional. Rb1+ is bonded in a 11-coordinate geometry to eleven F1- atoms. There are a spread of Rb–F bond distances ranging from 2.94–3.29 Å. There are two inequivalent Pd2+ sites. In the first Pd2+ site, Pd2+ is bonded to six F1- atoms to form corner-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles are 55°. All Pd–F bond lengths are 2.20 Å. In the second Pd2+ site, Pd2+ is bonded in a square co-planar geometry to four equivalent F1- atoms. All Pd–F bond lengths are 2.00 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a 2-coordinate geometry to two equivalent Rb1+ and two Pd2+ atoms. In the second F1- site, F1- is bonded in a 2-coordinate geometry to three equivalent Rb1+ and two equivalent Pd2+ atoms.},
doi = {10.17188/1312863},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}