U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Ti3Tl by Materials Project
Abstract
Ti3Tl is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded to eight Ti and four equivalent Tl atoms to form TiTi8Tl4 cuboctahedra that share corners with twelve equivalent TiTi8Tl4 cuboctahedra, edges with eight equivalent TlTi12 cuboctahedra, edges with sixteen TiTi8Tl4 cuboctahedra, faces with four equivalent TlTi12 cuboctahedra, and faces with fourteen TiTi8Tl4 cuboctahedra. There are four shorter (2.88 Å) and four longer (3.01 Å) Ti–Ti bond lengths. All Ti–Tl bond lengths are 3.01 Å. In the second Ti site, Ti is bonded to eight equivalent Ti and four equivalent Tl atoms to form TiTi8Tl4 cuboctahedra that share corners with four equivalent TiTi8Tl4 cuboctahedra, corners with eight equivalent TlTi12 cuboctahedra, edges with twenty-four TiTi8Tl4 cuboctahedra, faces with six equivalent TlTi12 cuboctahedra, and faces with twelve TiTi8Tl4 cuboctahedra. All Ti–Tl bond lengths are 2.88 Å. Tl is bonded to twelve Ti atoms to form TlTi12 cuboctahedra that share corners with four equivalent TlTi12 cuboctahedra, corners with eight equivalent TiTi8Tl4 cuboctahedra, edges with eight equivalent TlTi12 cuboctahedra, edges with sixteen equivalent TiTi8Tl4 cuboctahedra, faces with four equivalent TlTi12 cuboctahedra, and faces withmore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-865900
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Ti3Tl; Ti-Tl
- OSTI Identifier:
- 1311078
- DOI:
- https://doi.org/10.17188/1311078
Citation Formats
The Materials Project. Materials Data on Ti3Tl by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1311078.
The Materials Project. Materials Data on Ti3Tl by Materials Project. United States. doi:https://doi.org/10.17188/1311078
The Materials Project. 2020.
"Materials Data on Ti3Tl by Materials Project". United States. doi:https://doi.org/10.17188/1311078. https://www.osti.gov/servlets/purl/1311078. Pub date:Mon Jul 20 00:00:00 EDT 2020
@article{osti_1311078,
title = {Materials Data on Ti3Tl by Materials Project},
author = {The Materials Project},
abstractNote = {Ti3Tl is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded to eight Ti and four equivalent Tl atoms to form TiTi8Tl4 cuboctahedra that share corners with twelve equivalent TiTi8Tl4 cuboctahedra, edges with eight equivalent TlTi12 cuboctahedra, edges with sixteen TiTi8Tl4 cuboctahedra, faces with four equivalent TlTi12 cuboctahedra, and faces with fourteen TiTi8Tl4 cuboctahedra. There are four shorter (2.88 Å) and four longer (3.01 Å) Ti–Ti bond lengths. All Ti–Tl bond lengths are 3.01 Å. In the second Ti site, Ti is bonded to eight equivalent Ti and four equivalent Tl atoms to form TiTi8Tl4 cuboctahedra that share corners with four equivalent TiTi8Tl4 cuboctahedra, corners with eight equivalent TlTi12 cuboctahedra, edges with twenty-four TiTi8Tl4 cuboctahedra, faces with six equivalent TlTi12 cuboctahedra, and faces with twelve TiTi8Tl4 cuboctahedra. All Ti–Tl bond lengths are 2.88 Å. Tl is bonded to twelve Ti atoms to form TlTi12 cuboctahedra that share corners with four equivalent TlTi12 cuboctahedra, corners with eight equivalent TiTi8Tl4 cuboctahedra, edges with eight equivalent TlTi12 cuboctahedra, edges with sixteen equivalent TiTi8Tl4 cuboctahedra, faces with four equivalent TlTi12 cuboctahedra, and faces with fourteen TiTi8Tl4 cuboctahedra.},
doi = {10.17188/1311078},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}