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Title: Materials Data on LiSiBiO4 by Materials Project

Abstract

LiSiBiO4 crystallizes in the trigonal P31c space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 trigonal pyramids that share corners with four equivalent SiO4 tetrahedra. There is one shorter (1.87 Å) and three longer (1.94 Å) Li–O bond length. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with four equivalent LiO4 trigonal pyramids. There is one shorter (1.61 Å) and three longer (1.66 Å) Si–O bond length. Bi3+ is bonded in a 3-coordinate geometry to three equivalent O2- atoms. All Bi–O bond lengths are 2.17 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to one Li1+, one Si4+, and one Bi3+ atom. In the second O2- site, O2- is bonded in a linear geometry to one Li1+ and one Si4+ atom.

Authors:
Publication Date:
Other Number(s):
mp-863062
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; LiSiBiO4; Bi-Li-O-Si
OSTI Identifier:
1309810
DOI:
https://doi.org/10.17188/1309810

Citation Formats

The Materials Project. Materials Data on LiSiBiO4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1309810.
The Materials Project. Materials Data on LiSiBiO4 by Materials Project. United States. doi:https://doi.org/10.17188/1309810
The Materials Project. 2020. "Materials Data on LiSiBiO4 by Materials Project". United States. doi:https://doi.org/10.17188/1309810. https://www.osti.gov/servlets/purl/1309810. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1309810,
title = {Materials Data on LiSiBiO4 by Materials Project},
author = {The Materials Project},
abstractNote = {LiSiBiO4 crystallizes in the trigonal P31c space group. The structure is three-dimensional. Li1+ is bonded to four O2- atoms to form LiO4 trigonal pyramids that share corners with four equivalent SiO4 tetrahedra. There is one shorter (1.87 Å) and three longer (1.94 Å) Li–O bond length. Si4+ is bonded to four O2- atoms to form SiO4 tetrahedra that share corners with four equivalent LiO4 trigonal pyramids. There is one shorter (1.61 Å) and three longer (1.66 Å) Si–O bond length. Bi3+ is bonded in a 3-coordinate geometry to three equivalent O2- atoms. All Bi–O bond lengths are 2.17 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to one Li1+, one Si4+, and one Bi3+ atom. In the second O2- site, O2- is bonded in a linear geometry to one Li1+ and one Si4+ atom.},
doi = {10.17188/1309810},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}