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Title: Materials Data on Lu2Ge2O7 by Materials Project

Abstract

Lu2Ge2O7 crystallizes in the tetragonal P4_12_12 space group. The structure is three-dimensional. Lu3+ is bonded to seven O2- atoms to form distorted LuO7 pentagonal bipyramids that share corners with five equivalent GeO4 tetrahedra, edges with five equivalent LuO7 pentagonal bipyramids, and an edgeedge with one GeO4 tetrahedra. There are a spread of Lu–O bond distances ranging from 2.19–2.51 Å. Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share corners with five equivalent LuO7 pentagonal bipyramids, a cornercorner with one GeO4 tetrahedra, and an edgeedge with one LuO7 pentagonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.80 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to two equivalent Lu3+ and one Ge4+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Ge4+ atoms. In the third O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Lu3+ and one Ge4+ atom. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to three equivalent Lu3+ and one Ge4+ atom.

Authors:
Publication Date:
Other Number(s):
mp-8346
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Lu2Ge2O7; Ge-Lu-O
OSTI Identifier:
1308045
DOI:
https://doi.org/10.17188/1308045

Citation Formats

The Materials Project. Materials Data on Lu2Ge2O7 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1308045.
The Materials Project. Materials Data on Lu2Ge2O7 by Materials Project. United States. doi:https://doi.org/10.17188/1308045
The Materials Project. 2020. "Materials Data on Lu2Ge2O7 by Materials Project". United States. doi:https://doi.org/10.17188/1308045. https://www.osti.gov/servlets/purl/1308045. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1308045,
title = {Materials Data on Lu2Ge2O7 by Materials Project},
author = {The Materials Project},
abstractNote = {Lu2Ge2O7 crystallizes in the tetragonal P4_12_12 space group. The structure is three-dimensional. Lu3+ is bonded to seven O2- atoms to form distorted LuO7 pentagonal bipyramids that share corners with five equivalent GeO4 tetrahedra, edges with five equivalent LuO7 pentagonal bipyramids, and an edgeedge with one GeO4 tetrahedra. There are a spread of Lu–O bond distances ranging from 2.19–2.51 Å. Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share corners with five equivalent LuO7 pentagonal bipyramids, a cornercorner with one GeO4 tetrahedra, and an edgeedge with one LuO7 pentagonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.80 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to two equivalent Lu3+ and one Ge4+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two equivalent Ge4+ atoms. In the third O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Lu3+ and one Ge4+ atom. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to three equivalent Lu3+ and one Ge4+ atom.},
doi = {10.17188/1308045},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}