Materials Data on VP4 by Materials Project
Abstract
VP4 is Sylvanite-derived structured and crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. V4+ is bonded to six P1- atoms to form edge-sharing VP6 octahedra. There are a spread of V–P bond distances ranging from 2.35–2.42 Å. There are two inequivalent P1- sites. In the first P1- site, P1- is bonded in a 4-coordinate geometry to one V4+ and three P1- atoms. There are two shorter (2.23 Å) and one longer (2.25 Å) P–P bond lengths. In the second P1- site, P1- is bonded in a 4-coordinate geometry to two equivalent V4+ and two P1- atoms. The P–P bond length is 2.22 Å.
- Authors:
- Publication Date:
- Other Number(s):
- mp-8251
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; VP4; P-V
- OSTI Identifier:
- 1307991
- DOI:
- https://doi.org/10.17188/1307991
Citation Formats
The Materials Project. Materials Data on VP4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1307991.
The Materials Project. Materials Data on VP4 by Materials Project. United States. doi:https://doi.org/10.17188/1307991
The Materials Project. 2020.
"Materials Data on VP4 by Materials Project". United States. doi:https://doi.org/10.17188/1307991. https://www.osti.gov/servlets/purl/1307991. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1307991,
title = {Materials Data on VP4 by Materials Project},
author = {The Materials Project},
abstractNote = {VP4 is Sylvanite-derived structured and crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. V4+ is bonded to six P1- atoms to form edge-sharing VP6 octahedra. There are a spread of V–P bond distances ranging from 2.35–2.42 Å. There are two inequivalent P1- sites. In the first P1- site, P1- is bonded in a 4-coordinate geometry to one V4+ and three P1- atoms. There are two shorter (2.23 Å) and one longer (2.25 Å) P–P bond lengths. In the second P1- site, P1- is bonded in a 4-coordinate geometry to two equivalent V4+ and two P1- atoms. The P–P bond length is 2.22 Å.},
doi = {10.17188/1307991},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 16 00:00:00 EDT 2020},
month = {Thu Jul 16 00:00:00 EDT 2020}
}
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