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Title: Materials Data on VP4 by Materials Project

Abstract

VP4 is Sylvanite-derived structured and crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. V4+ is bonded to six P1- atoms to form edge-sharing VP6 octahedra. There are a spread of V–P bond distances ranging from 2.35–2.42 Å. There are two inequivalent P1- sites. In the first P1- site, P1- is bonded in a 4-coordinate geometry to one V4+ and three P1- atoms. There are two shorter (2.23 Å) and one longer (2.25 Å) P–P bond lengths. In the second P1- site, P1- is bonded in a 4-coordinate geometry to two equivalent V4+ and two P1- atoms. The P–P bond length is 2.22 Å.

Authors:
Publication Date:
Other Number(s):
mp-8251
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; VP4; P-V
OSTI Identifier:
1307991
DOI:
https://doi.org/10.17188/1307991

Citation Formats

The Materials Project. Materials Data on VP4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1307991.
The Materials Project. Materials Data on VP4 by Materials Project. United States. doi:https://doi.org/10.17188/1307991
The Materials Project. 2020. "Materials Data on VP4 by Materials Project". United States. doi:https://doi.org/10.17188/1307991. https://www.osti.gov/servlets/purl/1307991. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1307991,
title = {Materials Data on VP4 by Materials Project},
author = {The Materials Project},
abstractNote = {VP4 is Sylvanite-derived structured and crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. V4+ is bonded to six P1- atoms to form edge-sharing VP6 octahedra. There are a spread of V–P bond distances ranging from 2.35–2.42 Å. There are two inequivalent P1- sites. In the first P1- site, P1- is bonded in a 4-coordinate geometry to one V4+ and three P1- atoms. There are two shorter (2.23 Å) and one longer (2.25 Å) P–P bond lengths. In the second P1- site, P1- is bonded in a 4-coordinate geometry to two equivalent V4+ and two P1- atoms. The P–P bond length is 2.22 Å.},
doi = {10.17188/1307991},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}