Materials Data on Tb5O9 by Materials Project
Abstract
Tb5O9 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are two inequivalent Tb+3.60+ sites. In the first Tb+3.60+ site, Tb+3.60+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Tb–O bond distances ranging from 2.30–2.45 Å. In the second Tb+3.60+ site, Tb+3.60+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.31 Å) and four longer (2.52 Å) Tb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Tb+3.60+ atoms to form a mixture of edge and corner-sharing OTb4 tetrahedra. In the second O2- site, O2- is bonded to four Tb+3.60+ atoms to form a mixture of edge and corner-sharing OTb4 tetrahedra. In the third O2- site, O2- is bonded to four Tb+3.60+ atoms to form a mixture of distorted edge and corner-sharing OTb4 tetrahedra.
- Authors:
- Publication Date:
- Other Number(s):
- mp-780625
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Tb5O9; O-Tb
- OSTI Identifier:
- 1307132
- DOI:
- https://doi.org/10.17188/1307132
Citation Formats
The Materials Project. Materials Data on Tb5O9 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1307132.
The Materials Project. Materials Data on Tb5O9 by Materials Project. United States. doi:https://doi.org/10.17188/1307132
The Materials Project. 2020.
"Materials Data on Tb5O9 by Materials Project". United States. doi:https://doi.org/10.17188/1307132. https://www.osti.gov/servlets/purl/1307132. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1307132,
title = {Materials Data on Tb5O9 by Materials Project},
author = {The Materials Project},
abstractNote = {Tb5O9 crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are two inequivalent Tb+3.60+ sites. In the first Tb+3.60+ site, Tb+3.60+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Tb–O bond distances ranging from 2.30–2.45 Å. In the second Tb+3.60+ site, Tb+3.60+ is bonded in a body-centered cubic geometry to eight O2- atoms. There are four shorter (2.31 Å) and four longer (2.52 Å) Tb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Tb+3.60+ atoms to form a mixture of edge and corner-sharing OTb4 tetrahedra. In the second O2- site, O2- is bonded to four Tb+3.60+ atoms to form a mixture of edge and corner-sharing OTb4 tetrahedra. In the third O2- site, O2- is bonded to four Tb+3.60+ atoms to form a mixture of distorted edge and corner-sharing OTb4 tetrahedra.},
doi = {10.17188/1307132},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jul 18 00:00:00 EDT 2020},
month = {Sat Jul 18 00:00:00 EDT 2020}
}