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Title: Materials Data on Ge2N2O by Materials Project

Abstract

Ge2N2O crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are eight inequivalent Ge4+ sites. In the first Ge4+ site, Ge4+ is bonded to two N3- and two O2- atoms to form corner-sharing GeN2O2 tetrahedra. There is one shorter (1.83 Å) and one longer (1.84 Å) Ge–N bond length. There is one shorter (1.78 Å) and one longer (1.87 Å) Ge–O bond length. In the second Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.77–1.85 Å. The Ge–O bond length is 1.96 Å. In the third Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There is two shorter (1.86 Å) and one longer (1.87 Å) Ge–N bond length. The Ge–O bond length is 1.80 Å. In the fourth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.83–1.85 Å. The Ge–O bond length is 1.79 Å. In the fifth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atommore » to form corner-sharing GeN3O tetrahedra. There is two shorter (1.86 Å) and one longer (1.87 Å) Ge–N bond length. The Ge–O bond length is 1.79 Å. In the sixth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There is one shorter (1.83 Å) and two longer (1.85 Å) Ge–N bond length. The Ge–O bond length is 1.80 Å. In the seventh Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.77–1.87 Å. The Ge–O bond length is 2.02 Å. In the eighth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.84–1.86 Å. The Ge–O bond length is 1.79 Å. There are eight inequivalent N3- sites. In the first N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the second N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the third N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the fourth N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Ge4+ atoms. In the fifth N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the sixth N3- site, N3- is bonded in a bent 120 degrees geometry to two Ge4+ atoms. In the seventh N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Ge4+ atoms. In the eighth N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Ge4+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to two Ge4+ atoms. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to two Ge4+ atoms. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to two Ge4+ atoms.« less

Publication Date:
Other Number(s):
mp-779457
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ge2N2O; Ge-N-O
OSTI Identifier:
1306399
DOI:
10.17188/1306399

Citation Formats

The Materials Project. Materials Data on Ge2N2O by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1306399.
The Materials Project. Materials Data on Ge2N2O by Materials Project. United States. doi:10.17188/1306399.
The Materials Project. 2020. "Materials Data on Ge2N2O by Materials Project". United States. doi:10.17188/1306399. https://www.osti.gov/servlets/purl/1306399. Pub date:Tue Jul 14 00:00:00 EDT 2020
@article{osti_1306399,
title = {Materials Data on Ge2N2O by Materials Project},
author = {The Materials Project},
abstractNote = {Ge2N2O crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are eight inequivalent Ge4+ sites. In the first Ge4+ site, Ge4+ is bonded to two N3- and two O2- atoms to form corner-sharing GeN2O2 tetrahedra. There is one shorter (1.83 Å) and one longer (1.84 Å) Ge–N bond length. There is one shorter (1.78 Å) and one longer (1.87 Å) Ge–O bond length. In the second Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.77–1.85 Å. The Ge–O bond length is 1.96 Å. In the third Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There is two shorter (1.86 Å) and one longer (1.87 Å) Ge–N bond length. The Ge–O bond length is 1.80 Å. In the fourth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.83–1.85 Å. The Ge–O bond length is 1.79 Å. In the fifth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There is two shorter (1.86 Å) and one longer (1.87 Å) Ge–N bond length. The Ge–O bond length is 1.79 Å. In the sixth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There is one shorter (1.83 Å) and two longer (1.85 Å) Ge–N bond length. The Ge–O bond length is 1.80 Å. In the seventh Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.77–1.87 Å. The Ge–O bond length is 2.02 Å. In the eighth Ge4+ site, Ge4+ is bonded to three N3- and one O2- atom to form corner-sharing GeN3O tetrahedra. There are a spread of Ge–N bond distances ranging from 1.84–1.86 Å. The Ge–O bond length is 1.79 Å. There are eight inequivalent N3- sites. In the first N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the second N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the third N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the fourth N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Ge4+ atoms. In the fifth N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. In the sixth N3- site, N3- is bonded in a bent 120 degrees geometry to two Ge4+ atoms. In the seventh N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Ge4+ atoms. In the eighth N3- site, N3- is bonded in a trigonal planar geometry to three Ge4+ atoms. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Ge4+ atoms. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to two Ge4+ atoms. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to two Ge4+ atoms. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to two Ge4+ atoms.},
doi = {10.17188/1306399},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

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