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Title: Materials Data on Li2VO2 by Materials Project

Abstract

Li2VO2 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Li1+ is bonded to four equivalent O2- atoms to form LiO4 tetrahedra that share corners with six equivalent VO6 octahedra, corners with six equivalent LiO4 tetrahedra, edges with three equivalent VO6 octahedra, and edges with three equivalent LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 15–56°. There are three shorter (1.98 Å) and one longer (2.05 Å) Li–O bond lengths. V2+ is bonded to six equivalent O2- atoms to form VO6 octahedra that share corners with twelve equivalent LiO4 tetrahedra, edges with six equivalent VO6 octahedra, and edges with six equivalent LiO4 tetrahedra. All V–O bond lengths are 2.24 Å. O2- is bonded in a 7-coordinate geometry to four equivalent Li1+ and three equivalent V2+ atoms.

Publication Date:
Other Number(s):
mp-774411
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Li2VO2; Li-O-V
OSTI Identifier:
1302570
DOI:
https://doi.org/10.17188/1302570

Citation Formats

The Materials Project. Materials Data on Li2VO2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1302570.
The Materials Project. Materials Data on Li2VO2 by Materials Project. United States. doi:https://doi.org/10.17188/1302570
The Materials Project. 2020. "Materials Data on Li2VO2 by Materials Project". United States. doi:https://doi.org/10.17188/1302570. https://www.osti.gov/servlets/purl/1302570. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1302570,
title = {Materials Data on Li2VO2 by Materials Project},
author = {The Materials Project},
abstractNote = {Li2VO2 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Li1+ is bonded to four equivalent O2- atoms to form LiO4 tetrahedra that share corners with six equivalent VO6 octahedra, corners with six equivalent LiO4 tetrahedra, edges with three equivalent VO6 octahedra, and edges with three equivalent LiO4 tetrahedra. The corner-sharing octahedra tilt angles range from 15–56°. There are three shorter (1.98 Å) and one longer (2.05 Å) Li–O bond lengths. V2+ is bonded to six equivalent O2- atoms to form VO6 octahedra that share corners with twelve equivalent LiO4 tetrahedra, edges with six equivalent VO6 octahedra, and edges with six equivalent LiO4 tetrahedra. All V–O bond lengths are 2.24 Å. O2- is bonded in a 7-coordinate geometry to four equivalent Li1+ and three equivalent V2+ atoms.},
doi = {10.17188/1302570},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}